LATTICE-PARAMETERS OF ALKALI-METAL-DOPED C-60 FULLERIDES

被引：23

作者：

TANIGAKI, K

HIROSAWA, I

MIZUKI, J

EBBESEN, TW

机构：

[1] Fundamental Research Laboratories, Tsukuba, 305

来源：

CHEMICAL PHYSICS LETTERS | 1993年 / 213卷 / 3-4期

关键词：

D O I：

10.1016/0009-2614(93)85152-E

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Lattice constants of alkali-metal-doped A3C60 fullerides with face-centered cubic crystal structure are reported for a wide range of lattice parameters, using Li, Na, K, Rb, Cs and their binary mixtures. It is shown that the size of the alkali-metal cations in the tetrahedral interstitial sites controls the lattice parameters. The observed lattice parameters are discussed in comparison with other body-centered cubic A6C60 and rock salt type AlC60 phases. The field repulsive interactions among the C60 molecules other than the electrostatic Madelung energy must be taken into account to understand the lattice parameters of A3C60 in the small lattice parameter region, different from standard alkali-halide ionic crystals.

引用

页码：395 / 400

页数：6

共 25 条

[1] (RBXK1-X)3C60 SUPERCONDUCTORS - FORMATION OF A CONTINUOUS SERIES OF SOLID-SOLUTIONS [J].

CHEN, CC ;

KELTY, SP ;

LIEBER, CM .

SCIENCE, 1991, 253 (5022) :886-888

[2] RELATION OF STRUCTURE AND SUPERCONDUCTING TRANSITION-TEMPERATURES IN A3C60 [J].

FLEMING, RM ;

RAMIREZ, AP ;

ROSSEINSKY, MJ ;

MURPHY, DW ;

HADDON, RC ;

ZAHURAK, SM ;

MAKHIJA, AV .

NATURE, 1991, 352 (6338) :787-788

[3] PREPARATION AND STRUCTURE OF THE ALKALI-METAL FULLERIDE A4C60 [J].

FLEMING, RM ;

ROSSEINSKY, MJ ;

RAMIREZ, AP ;

MURPHY, DW ;

TULLY, JC ;

HADDON, RC ;

SIEGRIST, T ;

TYCKO, R ;

GLARUM, SH ;

MARSH, P ;

DABBAGH, G ;

ZAHURAK, SM ;

MAKHIJA, AV ;

HAMPTON, C .

NATURE, 1991, 352 (6337) :701-703

[4] MICROWAVE STUDY OF SUPERCONDUCTIVITY IN ALKALI-METAL-DOPED C-60 FILMS [J].

GLARUM, SH ;

DUCLOS, SJ ;

HADDON, RC .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (06) :1996-2001

[5] CONDUCTING FILMS OF C60 AND C70 BY ALKALI-METAL DOPING [J].

HADDON, RC ;

HEBARD, AF ;

ROSSEINSKY, MJ ;

MURPHY, DW ;

DUCLOS, SJ ;

LYONS, KB ;

MILLER, B ;

ROSAMILIA, JM ;

FLEMING, RM ;

KORTAN, AR ;

GLARUM, SH ;

MAKHIJA, AV ;

MULLER, AJ ;

EICK, RH ;

ZAHURAK, SM ;

TYCKO, R ;

DABBAGH, G ;

THIEL, FA .

NATURE, 1991, 350 (6316) :320-322

[6]

HEBARD AF, 1991, NATURE, V350, P660

[7] SITE SELECTIVE BEHAVIOR OF ALKALI-METALS IN BINARY DOPED C-60 [J].

HIROSAWA, I ;

TANIGAKI, K ;

MIZUKI, J ;

EBBESEN, TW ;

SHIMAKAWA, Y ;

KUBO, Y ;

KUROSHIMA, S .

SOLID STATE COMMUNICATIONS, 1992, 82 (12) :979-982

[8]

HIROSAWA I, UNPUB

[9] ALKALI-FULLERIDE SUPERCONDUCTORS - SYNTHESIS, COMPOSITION, AND DIAMAGNETIC SHIELDING [J].

HOLCZER, K ;

KLEIN, O ;

HUANG, SM ;

KANER, RB ;

FU, KJ ;

WHETTEN, RL ;

DIEDERICH, F .

SCIENCE, 1991, 252 (5009) :1154-1157

[10] CS-133 NMR IN C-60 SUPERCONDUCTORS - CSXRB3-XC60 (X=1,2) [J].

MANIWA, Y ;

MIZOGUCHI, K ;

KUME, K ;

TANIGAKI, K ;

EBBESEN, TW ;

SAITO, S ;

MIZUKI, J ;

TSAI, JS ;

KUBO, Y .

SOLID STATE COMMUNICATIONS, 1992, 82 (10) :783-785

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