ON THE PREPARATION OF BIS(TRIPHENYLSILYL)SULFANES (C6H5)3SI-SX-SI(C6H5)3 (X=3,4) AND THE CRYSTAL-STRUCTURE OF (C6H5)3SI-S4-SI(C6H5)3

被引：5

作者：

MINKWITZ, R

KORNATH, A

PREUT, H

机构：

[1] Fachbereich Anorganische Chemie, Universität Dortmund, D-44221

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 1994年 / 620卷 / 06期

关键词：

BIS(TRIPHENYLSILYL)SULFANES; PREPARATION; SINGLE CRYSTAL X-RAY STRUCTURE; VIBRATIONAL SPECTRA; NMR SPECTRA; UV-VIS SPECTRA;

D O I：

10.1002/zaac.19946200605

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The preparation of the bis(triphenylsilyl)sulfanes Ph3Si-Sx-SiPh3 (x = 3,4) from Ph3SiSNa and SCl2 resp. S2Cl2 is reported. They are characterized by vibrational, NMR and UV-VIS spectroscopic measurements. Ph3Si-S4-SiPh3 crystallizes in space group P1BAR with a = 943.6(6)pm, b = 945.7(5) pm, c = 1 881.7(12) pm, alpha = 82.11(5)-degrees, beta = 78.95(5)-degrees, gamma = 83.15(5)-degrees and Z = 2.

引用

页码：981 / 986

页数：6

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