ALKYLATION OF POTASSIUM ACETATE IN DRY MEDIA THERMAL-ACTIVATION IN COMMERCIAL MICROWAVE-OVENS

被引：171
作者：
BRAM, G
LOUPY, A
MAJDOUB, M
GUTIERREZ, E
RUIZHITZKY, E
机构：
[1] UNIV PARIS 11,ICMO,REACT SELECT SUPPORTS LAB,UA 478,BATIMENT 410,F-91405 ORSAY,FRANCE
[2] CSIC,INST CIENCIA MAT,E-28006 MADRID,SPAIN
来源：
TETRAHEDRON | 1990年 / 46卷 / 15期
关键词：
D O I：
10.1016/S0040-4020(01)87823-6
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Microwave irradiation using commercial domestic ovens is very efficient to activate potassium acetate on alumina in the absence of solvent ("dry media") giving rise to remarkable rate enhancements in alkylation reactions with long chain halides. These reactions can be performed quantitatively on appreciable amounts of materials in open standard pyrex vessels. © 1990.
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收藏
页码：5167 / 5176
页数：10
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