ESR STUDIES OF FLUORINATED FULLERENES - EVIDENCE FOR THE FORMATION OF ODD C-60FN SPECIES

被引：9
作者：
BELAISH, I
DAVIDOV, D
SELIG, H
FISCHER, JE
机构：
[1] HEBREW UNIV JERUSALEM,INST CHEM,JERUSALEM,ISRAEL
[2] UNIV PENN,RES STRUCT MATTER LAB,PHILADELPHIA,PA 19104
来源：
ADVANCED MATERIALS | 1992年 / 4卷 / 06期
关键词：
D O I：
10.1002/adma.19920040607
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Paramagnetic odd-fluorinated fullerenes have been observed and characterized by electron spin resonance (ESR), revealing evidence that the fluorination process is inhomogeneous and that these species are not very stable. It is suggested, therefore, that the only method of stabilizing odd fluorinated fullerenes would be to capture the fluorine inside the C60 cage. The relative stability of the various fluorinated fullerenes is discussed.
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收藏
页码：411 / 412
页数：2
相关论文
共 11 条
  • [1] 2 DIFFERENT FULLERENES HAVE THE SAME CYCLIC VOLTAMMETRY
    ALLEMAND, PM
    KOCH, A
    WUDL, F
    RUBIN, Y
    DIEDERICH, F
    ALVAREZ, MM
    ANZ, SJ
    WHETTEN, RL
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (03) : 1050 - 1051
  • [2] ATA M, 1991, COPENHAGEN C FULLERE
  • [3] BREIT G, 1931, PHYS REVV, V38, P2028
  • [4] CHARACTERIZATION OF C60 AND C70 CLUSTERS
    COX, DM
    BEHAL, S
    DISKO, M
    GORUN, SM
    GREANEY, M
    HSU, CS
    KOLLIN, EB
    MILLAR, J
    ROBBINS, J
    ROBBINS, W
    SHERWOOD, RD
    TINDALL, P
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (08) : 2940 - 2944
  • [5] ESR SPECTRA AND STRUCTURE OF FLUORINATED METHYL RADICALS
    FESSENDEN, RW
    SCHULER, RH
    [J]. JOURNAL OF CHEMICAL PHYSICS, 1965, 43 (08) : 2704 - +
  • [6] FOOTE CS, 1990, CHEM ENG NEWS, V68, P2
  • [7] FLUORINATION OF BUCKMINSTERFULLERENE
    HOLLOWAY, JH
    HOPE, EG
    TAYLOR, R
    LANGLEY, GJ
    AVENT, AG
    DENNIS, TJ
    HARE, JP
    KROTO, HW
    WALTON, DRM
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1991, (14) : 966 - 969
  • [8] FLUORINATED FULLERENES
    SELIG, H
    LIFSHITZ, C
    PERES, T
    FISCHER, JE
    MCGHIE, AR
    ROMANOW, WJ
    MCCAULEY, JP
    SMITH, AB
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (14) : 5475 - 5476
  • [9] TAYLOR R, IN PRESS J CHEM SOC
  • [10] MULTIPLE, REVERSIBLE CHLORINATION OF C-60
    TEBBE, FN
    BECKER, JY
    CHASE, DB
    FIRMENT, LE
    HOLLER, ER
    MALONE, BS
    KRUSIC, PJ
    WASSERMAN, E
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (26) : 9900 - 9901
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