EFFECTS OF EXTRACTION PROCEDURES ON FULVIC-ACID PROPERTIES

被引:21
作者
GREGOR, JE
POWELL, HKJ
机构
[1] Univ of Canterbury, Christchurch, NZ, Univ of Canterbury, Christchurch, NZ
关键词
ACIDS - Organic - ORGANIC COMPOUNDS - Extraction;
D O I
10.1016/0048-9697(87)90476-1
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
Acid pyrophosphate (pH 2-4) is proposed as an extractant for soil fulvic acids. After XAD treatment of the extractant solution low-ash fulvic acids are obtained in high yield. The fulvic acids were subjected to the high pH and low pH conditions normally encountered in fulvic acid extraction. The observed changes induced in molecular weight distribution, equivalent weight, acid dissociation constants (pK//i) and metal binding strength are reported.
引用
收藏
页码:3 / 12
页数:10
相关论文
共 18 条
[1]   COMPARISON OF XAD MACROPOROUS RESINS FOR THE CONCENTRATION OF FULVIC-ACID FROM AQUEOUS-SOLUTION [J].
AIKEN, GR ;
THURMAN, EM ;
MALCOLM, RL ;
WALTON, HF .
ANALYTICAL CHEMISTRY, 1979, 51 (11) :1799-1803
[2]   TITRATIONS OF FULVIC-ACID FRACTIONS .1. INTERACTIONS INFLUENCING THE DISSOCIATION-REPROTONATION EQUILIBRIA [J].
DAVIS, H ;
MOTT, CJB .
JOURNAL OF SOIL SCIENCE, 1981, 32 (03) :379-391
[4]   FLUORESCENCE EXCITATION-SPECTRA AND VISCOSITY BEHAVIOR OF A FULVIC-ACID AND ITS COPPER AND IRON COMPLEXES [J].
GHOSH, K ;
SCHNITZER, M .
SOIL SCIENCE SOCIETY OF AMERICA JOURNAL, 1981, 45 (01) :25-29
[5]   DETERMINATION OF THE EQUIVALENCE POINT IN POTENTIOMETRIC TITRATIONS .2. [J].
GRAN, G .
ANALYST, 1952, 77 (920) :661-671
[6]  
GREGOR JE, IN PRESS J SOIL SCI
[7]  
MIHAILOVIC ML, 1971, CHEM HYDROXYL GROU 1
[8]   ACID-BASE PROPERTIES OF AQUATIC FULVIC-ACID [J].
PAXEUS, N ;
WEDBORG, M .
ANALYTICA CHIMICA ACTA, 1985, 169 (MAR) :87-98
[9]  
Perrin D. D., 1979, STABILITY CONSTANT B
[10]   INTERACTIONS OF IRON(II) AND IRON(III) WITH GALLIC ACID AND ITS HOMOLOGS - A POTENTIOMETRIC AND SPECTROPHOTOMETRIC STUDY [J].
POWELL, HKJ ;
TAYLOR, MC .
AUSTRALIAN JOURNAL OF CHEMISTRY, 1982, 35 (04) :739-756