ANALYSIS OF THE IMPEDANCE RESPONSE OF PASSIVE IRON

被引：36

作者：

CASTRO, EB

机构：

[1] Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas (INIFTA), Facultad de Ciencias Exactas, Universidad Nacional de La Plata, 1900 La Plata, Sucursal 4

来源：

ELECTROCHIMICA ACTA | 1994年 / 39卷 / 14期

关键词：

PASSIVE LAYERS; ANODIC OXIDE FILMS; IRON; ELECTROCHEMICAL IMPEDANCE SPECTROSCOPY; PASSIVITY;

D O I：

10.1016/0013-4686(94)E0172-V

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

The impedance response of passive iron is described in terms of a model that takes into account the electrochemical processes taking place at both the metal/oxide and oxide/electrolyte interfaces and the influence of the ionic transport in the passive film. The comparison of the theoretical transfer function with experimental data corresponding to iron passivated in aqueous boric acid-borate buffers leads to the conclusion that the potential perturbing signal does not interfere with the equilibrium of the layer formation reactions (deposition and removal of oxygen ions), the faradaic impedance being related to the iron dissolution through the passive film.

引用

页码：2117 / 2123

页数：7

共 21 条

[1] IMPEDANCE OF METALS IN PASSIVE AND TRANSPASSIVE REGIONS [J].

ARMSTRONG, RD ;

EDMONDSON, K .

ELECTROCHIMICA ACTA, 1973, 18 (12) :937-943

[2]

CABRERA N, 1948, REP PROG PHYS, V12, P267

[3] STUDY OF IRON ELECTRODISSOLUTION IN CARBONATE BICARBONATE SOLUTIONS BY ELECTROCHEMICAL IMPEDANCE SPECTROSCOPY [J].

CASTRO, EB ;

VILCHE, JR .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1992, 323 (1-2) :231-246

[4] INVESTIGATION OF PASSIVE LAYERS ON IRON AND IRON-CHROMIUM ALLOYS BY ELECTROCHEMICAL IMPEDANCE SPECTROSCOPY [J].

CASTRO, EB ;

VILCHE, JR .

ELECTROCHIMICA ACTA, 1993, 38 (11) :1567-1572

[5] A POINT-DEFECT MODEL FOR ANODIC PASSIVE FILMS .3. IMPEDANCE RESPONSE [J].

CHAO, CY ;

LIN, LF ;

MACDONALD, DD .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1982, 129 (09) :1874-1879

[6] THE NATURE OF THE PASSIVE FILM ON IRON .1. AUTOMATIC ELLIPSOMETRIC SPECTROSCOPY STUDIES [J].

CHEN, CT ;

CAHAN, BD .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1982, 129 (01) :17-26

[7]

Fromhold A. T., 1976, OXIDE OXIDE FILMS, V4, P1

[8] DIFFUSION CURRENTS IN LARGE ELECTRIC FIELDS FOR DISCRETE LATTICES [J].

FROMHOLD, AT ;

COOK, EL .

JOURNAL OF APPLIED PHYSICS, 1967, 38 (04) :1546-&

[9] REMARKS ON THE ELECTRONIC-STRUCTURE OF THE OXIDE FILM ON PASSIVE IRON AND THE CONSEQUENCES FOR ITS ELECTRODE BEHAVIOR [J].

GERISCHER, H .

CORROSION SCIENCE, 1989, 29 (2-3) :191-195

[10] REACTION MODEL FOR IRON DISSOLUTION STUDIED BY ELECTRODE IMPEDANCE .1. EXPERIMENTAL RESULTS AND REACTION MODEL [J].

KEDDAM, M ;

MATTOS, OR ;

TAKENOUTI, H .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1981, 128 (02) :257-266

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