REACTIVITY OF PENTAMETHYLCYCLOPENTADIENYLTETRACHLOROMOLYBDENUM(V) - SYNTHESIS, STRUCTURE AND ELECTROCHEMICAL PROPERTIES OF [(ETA-5-C5ME5)MOOCL]2O

被引：21

作者：

UMAKOSHI, K ^{[1
]}

ISOBE, K ^{[1
]}

机构：

[1] INST MOLEC SCI,DEPT APPL MOLEC SCI,OKAZAKI,AICHI 444,JAPAN

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1990年 / 395卷 / 01期

关键词：

D O I：

10.1016/0022-328X(90)85261-V

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of [(η5-C5Me5)MoVCl4] with Na2WO4 in THF provides red-brown [(η5-C5Me5)MoVOCl]2O, while in water yellow [(η5-C5Me5)MoVIO2]2O is formed. Single-crystal X-ray diffraction analysis has revealed that [(η5-C5Me5)MoOCl]2O has an anti configuration with a linear MoOMo skeleton. A cyclic voltammogram of [(η5-C5Me5)MoOCl]2O in CH2Cl2 shows both a reversible and an irreversible two-electron process centered at -0.70 V and +1.03 V vs Ag/AgCl, respectively. Crystal data: monoclinic, space group P21/n, a 10.621(1), b 14.371(3), c 7.689(1) Å, β 93.24(2)o, Z = 2. © 1990.

引用

页码：47 / 53

页数：7

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