ANOMALOUS SYMMETRIES OF THE ROVIBRATIONAL STATES OF HO2 - CONSEQUENCES OF A CONICAL INTERSECTION

被引：34

作者：

BARCLAY, VJ ^{[1
]}

DATEO, CE ^{[1
]}

HAMILTON, IP ^{[1
]}

KENDRICK, B ^{[1
]}

PACK, RT ^{[1
]}

SCHWENKE, DW ^{[1
]}

机构：

[1] LOS ALAMOS NATL LAB, DIV THEORET T12 MS B268, LOS ALAMOS, NM 87545 USA

来源：

JOURNAL OF CHEMICAL PHYSICS | 1995年 / 103卷 / 09期

关键词：

D O I：

10.1063/1.470039

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

We show that the geometric phase arising from a conical intersection of the lowest potential energy surfaces of HO2 causes its bending vibrational wave functions to be double-valued, which enables them to be locally symmetric on one side of the intersection and locally antisymmetric on the other. (C) 1995 American institute of Physics.

引用

页码：3864 / 3867

页数：4

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