EVIDENCE FOR A REVERSIBLE D,PI-STAR-COMPLEXATION, BETA-CUPRATION SEQUENCE IN THE CONJUGATE ADDITION-REACTION OF GILMAN REAGENTS WITH ALPHA-ENONES, BETA-ENONES

被引：384
作者：
COREY, EJ
BOAZ, NW
机构：
来源：
TETRAHEDRON LETTERS | 1985年 / 26卷 / 49期
关键词：
D O I：
10.1016/S0040-4039(00)95113-X
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
引用
收藏
页码：6015 / 6018
页数：4
相关论文
共 17 条
[1]   STUDIES IN PROSTAGLANDINS .9. SYNTHESIS OF (+1-)-PROSTAGLANDIN-E1, (+1-)-11-DEOZYPROSTAGLANDINS-E1, F1ALPHA, AND F1BETA, AND (+1-)-9-OXO-13-CIS-PROSTENOIC ACID BY CONJUGATE ADDITION OF VINYLCOPPER REAGENTS [J].
ALVAREZ, FS ;
WREN, D ;
PRINCE, A .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1972, 94 (22) :7823-&
[2]  
CHEREST M, 1968, TETRAHEDRON LETT, P2199
[3]   THE REACTIONS OF COMBINED ORGANOCUPRATE CHLOROTRIMETHYLSILANE REAGENTS WITH CONJUGATED CARBONYL-COMPOUNDS [J].
COREY, EJ ;
BOAZ, NW .
TETRAHEDRON LETTERS, 1985, 26 (49) :6019-6022
[4]   D-ORBITAL STEREOELECTRONIC CONTROL OF THE STEREOCHEMISTRY OF SN2' DISPLACEMENTS BY ORGANOCUPRATE REAGENTS [J].
COREY, EJ ;
BOAZ, NW .
TETRAHEDRON LETTERS, 1984, 25 (29) :3063-3066
[5]   AN NMR INVESTIGATION OF THE REACTION BETWEEN CINNAMIC ACID-ESTERS AND LITHIUM DIMETHYLCUPRATE - INITIAL FORMATION OF AN OLEFIN-COPPER PI-COMPLEX [J].
HALLNEMO, G ;
OLSSON, T ;
ULLENIUS, C .
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1985, 282 (01) :133-144
[6]   REACTIONS INVOLVING ELECTRON-TRANSFER .7. USE OF INTRAMOLECULAR REACTIONS AS A TEST FOR ANION RADICAL INTERMEDIATES [J].
HOUSE, HO ;
WEEKS, PD .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1975, 97 (10) :2778-2785
[7]   USE OF LITHIUM ORGANOCUPRATE ADDITIONS AS MODELS FOR AN ELECTRON-TRANSFER PROCESS [J].
HOUSE, HO .
ACCOUNTS OF CHEMICAL RESEARCH, 1976, 9 (02) :59-67
[8]   REACTIONS INVOLVING ELECTRON-TRANSFER .6. STEREOCHEMICAL TEST FOR ANION RADICAL INTERMEDIATES IN ADDITIONS TO CARBONYL-COMPOUNDS [J].
HOUSE, HO ;
WEEKS, PD .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1975, 97 (10) :2770-2777
[9]   A NEW EFFICIENT DECARBOXYLATIVE REDUCTION OF GAMMA-CARBAMOYLOXY-ALPHA,BETA-UNSATURATED ESTERS WITH LITHIUM DIALKYLCUPRATE [J].
IBUKA, T ;
CHU, GN ;
YONEDA, F .
TETRAHEDRON LETTERS, 1984, 25 (30) :3247-3250
[10]   KINETICS AND MECHANISM OF THE CONJUGATE ADDITION OF LITHIUM DIMETHYLCUPRATE TO ALPHA,BETA-UNSATURATED KETONES [J].
KRAUSS, SR ;
SMITH, SG .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1981, 103 (01) :141-148
12