EVIDENCES FOR BROMO-BRIDGED ONE-DIMENSIONAL CHAIN STRUCTURE OF THE MIXED-VALENCE GOLD COMPLEXES WITH THE EMPIRICAL FORMULAS, [AUBR2(DBS)] AND [AUBRCL(DBS)] (DBS = DIBENZYL SULFIDE)

被引:2
作者
TAKAHASHI, K [1 ]
TANINO, H [1 ]
机构
[1] ELECTROTECH LAB, TSUKUBA, IBARAKI 305, JAPAN
关键词
D O I
10.1246/cl.1991.1977
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The bromo-bridged one-dimensional chain structure of [AuBr2(DBS)] is revealed by X-ray analysis. The bromo-bridged skeleton of the one-dimensional chain of [AuBrCl(DBS)] is identified by comparing its unit cell parameters, visible absorption spectrum on nujol mull, and Br K near-edge X-ray absorption spectra with those of [AuBr2(DBS)].
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页码:1977 / 1980
页数:4
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