ADSORPTION AT THE AIR/WATER INTERFACE IN DODECYLAMMONIUM CHLORIDE SODIUM DODECYL-SULFATE MIXTURES

被引：17
|
作者：
DRAGCEVIC, D
BUJAN, M
GRAHEK, Z
FILIPOVICVINCEKOVIC, N
机构：
[1] RUDJER BOSKOVIC INST,DEPT CHEM PHYS,ZAGREB 10000,CROATIA
[2] RUDJER BOSKOVIC INST,FAC AGR,ZAGREB 10000,CROATIA
来源：
COLLOID AND POLYMER SCIENCE | 1995年 / 273卷 / 10期
关键词：
CATIONIC ANIONIC SURFACTANT MIXTURES; AIR/WATER INTERFACE; SURFACE POTENTIAL;
D O I：
10.1007/BF00660375
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The composition and properties of the adsorption films of dodecylammonium chloride/sodium dodecyl sulfate at the air/water interface depend on interactions between the film molecules and equilibria in the bulk phase (monomer-micelle and/or monomer-precipitate equilibria). The negative value of surface molecular interaction parameter beta(mon) calculated using the regular solution theory indicates strong attractive interactions between adsorbed molecules. Electrostatic interactions between oppositely charged ionic head groups enhance the adsorption of surfactants and decrease the minimum molar area of surfactant molecules at the air/water interface. The addition of an oppositely charged surfactant enhances packing at the air/water interface and transition from a liquid expanded to a liquid condensed state. Surface potential measurements reveal positive values for the mixtures investigated, implying the cationic surfactant ions are closer to the surface than the anionic ones.
引用
收藏
页码：967 / 973
页数：7
相关论文
共 50 条
  • [1] INTERACTIONS IN DODECYLAMMONIUM CHLORIDE DODECYL-SULFATE SYSTEMS
    FILIPOVICVINCEKOVIC, N
    SKRTIC, D
    TOMASIC, V
    BERICHTE DER BUNSEN-GESELLSCHAFT-PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 1991, 95 (12): : 1646 - 1651
  • [2] PRECIPITATION AND ASSOCIATION IN A MIXTURE OF DODECYLAMMONIUM CHLORIDE AND SODIUM DODECYL-SULFATE IN AQUEOUS-MEDIUM
    TOMASIC, V
    FILIPOVICVINCEKOVIC, N
    KOJICPRODIC, B
    KALLAY, N
    COLLOID AND POLYMER SCIENCE, 1991, 269 (12) : 1289 - 1294
  • [3] Adsorption of Mixtures of Poly(amidoamine) Dendrimers and Sodium Dodecyl Sulfate at the Air-Water Interface
    Arteta, Marianna Yanez
    Campbell, Richard A.
    Nylander, Tommy
    LANGMUIR, 2014, 30 (20) : 5817 - 5828
  • [4] GROWTH OF DODECYLAMMONIUM DODECYL-SULFATE CRYSTALS
    SKRTIC, D
    FILIPOVICVINCEKOVIC, N
    TOMASIC, V
    JOURNAL OF COLLOID AND INTERFACE SCIENCE, 1992, 151 (01) : 288 - 291
  • [5] ADSORPTION AT THE AIR-WATER-INTERFACE FROM AN AQUEOUS-SOLUTION OF POLY(VINYLPYRROLIDONE) AND SODIUM DODECYL-SULFATE
    CHARI, K
    HOSSAIN, TZ
    JOURNAL OF PHYSICAL CHEMISTRY, 1991, 95 (08): : 3302 - 3305
  • [6] Mixtures of sodium dodecyl sulfate/dodecanol at the air/water interface by computer simulations
    Domínguez, H
    Rivera, M
    LANGMUIR, 2005, 21 (16) : 7257 - 7262
  • [7] THE COMPOSITION AND STRUCTURE OF SODIUM DODECYL-SULFATE DODECANOL MIXTURES ADSORBED AT THE AIR-WATER-INTERFACE - A NEUTRON REFLECTION STUDY
    LU, JR
    PURCELL, IP
    LEE, EM
    SIMISTER, EA
    THOMAS, RK
    RENNIE, AR
    PENFOLD, J
    JOURNAL OF COLLOID AND INTERFACE SCIENCE, 1995, 174 (02) : 441 - 455
  • [8] Competitive adsorption of sodium dodecyl sulfate and polyethylene oxide at the air/water interface
    Peron, Nicolas
    Meszaros, Robert
    Varga, Imre
    Gilanyi, Tibor
    JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2007, 313 (02) : 389 - 397
  • [9] Adsorption of polymer/surfactant mixtures at the air-water interface: Ethoxylated poly(ethyleneimine) and sodium dodecyl sulfate
    Penfold, J
    Taylor, DJF
    Thomas, RK
    Tucker, I
    Thompson, LJ
    LANGMUIR, 2003, 19 (19) : 7740 - 7745
  • [10] Adsorption of Polyelectrolyte/Surfactant Mixtures at the Air-Water Interface: Modified Poly(ethyleneimine) and Sodium Dodecyl Sulfate
    Zhang, X. L.
    Taylor, D. J. F.
    Thomas, R. K.
    Penfold, J.
    LANGMUIR, 2011, 27 (06) : 2601 - 2612
12345