DESIGNATED MOLECULAR DECONSTRUCTION - THE FACILE TRANSFORMATION OF GA(N(SIME3)2)(OSIME3)2PY (PY = PYRIDINE) TO GAN

被引：22
作者：
BARRY, ST [1 ]
RICHESON, DS [1 ]
机构：
[1] UNIV OTTAWA,DEPT CHEM,OTTAWA,ON K1N 6N5,CANADA
来源：
CHEMISTRY OF MATERIALS | 1994年 / 6卷 / 12期
关键词：
D O I：
10.1021/cm00048a007
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The new complex Ga(N(SiMe3)2)(OSiMe3)2py undergoes a smooth thermolysis, as monitored by H-1 NMR and GC/MS, at 155-degrees-C to yield to gray powder, (Me3Si)2O, and free pyridine. The X-ray diffraction powder pattern of the gray powder evolves into that of hexagonal GaN upon heating. A related complex, [Li(THF)2][Ga(N(SiMe3)2)(OSiMe3)2Cl], is reported and characterized by single-crystal X-ray diffraction.
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页码：2220 / 2221
页数：2
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