DESIGNATED MOLECULAR DECONSTRUCTION - THE FACILE TRANSFORMATION OF GA(N(SIME3)2)(OSIME3)2PY (PY = PYRIDINE) TO GAN

被引：22

作者：

BARRY, ST ^{[1
]}

RICHESON, DS ^{[1
]}

机构：

[1] UNIV OTTAWA,DEPT CHEM,OTTAWA,ON K1N 6N5,CANADA

来源：

CHEMISTRY OF MATERIALS | 1994年 / 6卷 / 12期

关键词：

D O I：

10.1021/cm00048a007

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The new complex Ga(N(SiMe3)2)(OSiMe3)2py undergoes a smooth thermolysis, as monitored by H-1 NMR and GC/MS, at 155-degrees-C to yield to gray powder, (Me3Si)2O, and free pyridine. The X-ray diffraction powder pattern of the gray powder evolves into that of hexagonal GaN upon heating. A related complex, [Li(THF)2][Ga(N(SiMe3)2)(OSiMe3)2Cl], is reported and characterized by single-crystal X-ray diffraction.

引用

页码：2220 / 2221

页数：2

共 17 条

[1] ORGANOMETALLIC PRECURSORS FOR THE FORMATION OF GALLIUM NITRIDE BY METAL ORGANIC-CHEMICAL VAPOR-DEPOSITION - THERMAL-DECOMPOSITION OF TRINEOPENTYL GALLIUM AND OF ITS ADDUCTS WITH AMMONIA, DIMETHYLAMINE AND T-BUTYLAMINE [J].