METAL-PI-COMPLEXES OF HETEROARENES .3. BIS(ETA-6-PHOSPHABENZENE)VANADIUM - SYNTHESIS, STRUCTURE, REDOX PROPERTIES, AND CONFORMATIONAL FLEXIBILITY

被引：65
作者：
ELSCHENBROICH, C
NOWOTNY, M
METZ, B
MASSA, W
GRAULICH, J
BIEHLER, K
SAUER, W
机构：
[1] Fachbereich Chemie, Universität Marburg, W-3550, Hans-Meerwein-Strasse
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1991年 / 30卷 / 05期
关键词：
D O I：
10.1002/anie.199105471
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Metal-ligand condensation was used to prepare the first binary heteroarene complex of a group 15 metal, bis(eta-6-phosphabenzene)-vanadium (1). It was fully characterized by EPR spectroscopy, X-ray structure analysis, and cyclovoltammetry. In contrast to the free ligand and to the analogous benzene complex, 1 is thermally stable and is very stable toward oxidizing agents.
引用
收藏
页码：547 / 550
页数：4
相关论文
共 28 条
[1]  
ASHE AJ, 1982, TOP CURR CHEM, V105, P125
[2]   GROUP-5 HETEROBENZENES [J].
ASHE, AJ .
ACCOUNTS OF CHEMICAL RESEARCH, 1978, 11 (04) :153-157
[3]   PHOSPHABENZENE AND ARSABENZENE [J].
ASHE, AJ .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1971, 93 (13) :3293-&
[4]  
ASHE AJ, COMMUNICATION
[5]  
BATICH C, 1973, J AM CHEM SOC, V98, P928
[6]  
BILGER E, 1984, THESIS MARBURG
[7]   TEMPORARY ANION STATES OF PHOSPHABENZENE, ARSABENZENE, AND STIBABENZENE - TRENDS IN THE PI AND PI-STAR ORBITAL ENERGIES [J].
BURROW, PD ;
ASHE, AJ ;
BELLVILLE, DJ ;
JORDAN, KD .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1982, 104 (02) :425-429
[8]  
CLOKE FGN, 1938, J CHEM SOC DA 1981
[9]  
DAUL C, 1981, COMPUT PHYS COMMUN, V91, P385
[10]   TRICARBONYL(TRIPHENYLPHOSPHORINE)MOLYBDENUM(O) [J].
DEBERITZ, J ;
NOTH, H .
CHEMISCHE BERICHTE-RECUEIL, 1973, 106 (07) :2222-2226
123