Polymerization of phenylglycidylether derivatives with functional ester groups

被引：10

作者：

Ronda, JC ^{[1
]}

Serra, A ^{[1
]}

Mantecon, A ^{[1
]}

Cadiz, V ^{[1
]}

机构：

[1] UNIV ROVIRA & VIRGILI,FAC QUIM,DEPT QUIM QUIM ORGAN,E-43005 TARRAGONA,SPAIN

来源：

REACTIVE & FUNCTIONAL POLYMERS | 1995年 / 28卷 / 01期

关键词：

reactive polymers; phenylglycidylether; polyethers; ring opening; DSC; spacer group;

D O I：

10.1016/1381-5148(95)00053-8

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

A series of methyl <(omega)over bar>[p-(2,3-epoxypropoxy)phenyl] alkanoate esters of different lengths is prepared using a multistep synthetic method. These compounds which have 0, 1, 2, 5, 8 and 11 methylene groups are homopolymerized and copolymerized with non-functionalized phenylglycidyiether (PGE) using the ionic coordinative initiator described by Teyssie. Other ionic-coordinative initiators were found to be less effective. All homo- and copolymers are characterized by NMR spectroscopy and their tacticity is determined. Their thermal characteristics were also studied by DSC.

引用

页码：1 / 11

页数：11

共 19 条

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