AN ALKYL-SUBSTITUTED INDIUM(I) TETRAMER

被引：70

作者：

SCHLUTER, RD ^{[1
]}

COWLEY, AH ^{[1
]}

ATWOOD, DA ^{[1
]}

JONES, RA ^{[1
]}

ATWOOD, JL ^{[1
]}

机构：

[1] UNIV ALABAMA,DEPT CHEM,TUSCALOOSA,AL 35487

来源：

JOURNAL OF COORDINATION CHEMISTRY | 1993年 / 30卷 / 01期

关键词：

INDIUM(I); TETRAMER; STRUCTURE; REACTIVITY;

D O I：

10.1080/00958979308022744

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The first indium(I) alkyl, [InC(SiMe3)3]4 (1), has been prepared by treatment of InCl with LiC(SiMe3)3.2 THF in Et2O solution. Compound 1 crystallizes in the space group Pnma with a = 30.465(2), b = 13.855(2), c = 17.824(2)angstrom, and Z = 4. Individual molecules of 1 feature a tetrahedral In4 core with an average indium-indium distance of 3.09(2)angstrom.

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页码：25 / 28

页数：4

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