BETA-PHOSPHORYLATED 5-MEMBERED RING NITROXIDES, A NEW CLASS OF STABLE NITROXIDES .1. SYNTHESIS BY REACTION OF DIALKYLPHOSPHITES WITH 1-PYRROLINE-N-OXIDES

被引：24

作者：

MERCIER, A ^{[1
]}

BERCHADSKY, Y ^{[1
]}

BADRUDIN ^{[1
]}

PIETRI, S ^{[1
]}

TORDO, P ^{[1
]}

机构：

[1] UNIV AIX MARSEILLE 1,CTR ST JEROME,CNRS,UA 1412,STRUCT & REACT ESPECES PARAMAGNET LAB,F-13397 MARSEILLE 4,FRANCE

来源：

TETRAHEDRON LETTERS | 1991年 / 32卷 / 19期

关键词：

BETA-PHOSPHORYLATED 5-MEMBERED RING NITROXIDES; 1-PYRROLINE-N-OXIDES; ALPHA-PHOSPHORYLATED; ESR;

D O I：

10.1016/S0040-4039(00)71253-6

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Dialkylphosphites add to 2,5,5-trialkyl-1-pyrroline-N-oxides to give, after oxidation with copper(II)acetate, the corresponding beta-phosphorylated nitroxides, which are stable in many organic solvents.

引用

页码：2125 / 2128

页数：4

共 18 条

[1]

AYANT Y, 1990, C AMP MAGN RES REL P, P188

[2] NITRONES AND OXAZIRANS .I. PREPARATION OF 1-PYRROLINE 1-OXIDES AND 1-PYRROLINES BY REDUCTIVE CYCLIZATION OF GAMMA-NITRO CARBONYL COMPOUNDS [J].

BAPAT, JB ;

BLACK, DSC .

AUSTRALIAN JOURNAL OF CHEMISTRY, 1968, 21 (10) :2483-&

[3]

BERCHADSKY Y, Patent No. 2225015

[4]

BERLINER LJ, 1979, SPIN LABELING THEORY, V2

[5]

Berliner Lj, 1976, SEELING SPIN LABELLI

[6] NITRONES AND OXAZIRIDINES .8. CYCLOADDITION REACTIONS OF NITRONES WITH ISOTHIOCYANATES [J].

BLACK, DSC ;

WATSON, KG .

AUSTRALIAN JOURNAL OF CHEMISTRY, 1973, 26 (11) :2473-2489

[7] EXPERIMENTS TOWARDS THE SYNTHESIS OF CORRINS .2. THE PREPARATION AND REACTIONS OF DELTA-1-PYRROLINE 1-OXIDES [J].

BONNETT, R ;

BROWN, RFC ;

CLARK, VM ;

SUTHERLAND, IO ;

TODD, A .

JOURNAL OF THE CHEMICAL SOCIETY, 1959, (JUN) :2094-2102

[8] KINETIC APPLICATIONS OF ELECTRON PARAMAGNETIC RESONANCE SPECTROSCOPY .3. SELF-REACTIONS OF DIALKYL NITROXIDE RADICALS [J].

BOWMAN, DF ;

GILLAN, T ;

INGOLD, KU .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1971, 93 (24) :6555-&

[9] NITRONES .1. CYCLOADDITION OF UNSYMMETRICAL OLEFINS TO 1-PYRROLINE 1-OXIDES [J].

DELPIERRE, GR ;

LAMCHEN, M .

JOURNAL OF THE CHEMICAL SOCIETY, 1963, (OCT) :4693-&

[10]

FINKELSTEIN E, 1979, MOL PHARMACOL, V16, P676

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