2D POLYMERIC SILVER(I) COMPLEXES CONSISTING OF MARKEDLY UNDULATED SHEETS OF SQUARES - X-RAY CRYSTAL-STRUCTURES OF [AG(PPZ)(2)](BF4) AND [AG(PYZ)(2)](PF6) (PPZ=PIPERAZINE, PYZ=PYRAZINE)

被引：100
作者：
CARLUCCI, L
CIANI, G
PROSERPIO, DM
SIRONI, A
机构：
[1] UNIV MILAN, DIPARTIMENTO CHIM STRUTTURALE & STEREOCHIM, I-20133 MILAN, ITALY
[2] UNIV MILAN, CTR CNR, I-20133 MILAN, ITALY
来源：
INORGANIC CHEMISTRY | 1995年 / 34卷 / 22期
关键词：
D O I：
10.1021/ic00126a048
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Two novel silver(I) coordination polymers, [Ag(ppz)(2)](BF4) (1) and [Ag(pyz)(2)](PF6) (2) (ppz = piperazine, pyz = pyrazine), are prepared. Their crystal structures are found to contain markedly undulated 2D networks of distorted squares of Ag+ cations, in tetrahedral (1) and disphenoidal coordination geometries (2).
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页码：5698 / +
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