2D POLYMERIC SILVER(I) COMPLEXES CONSISTING OF MARKEDLY UNDULATED SHEETS OF SQUARES - X-RAY CRYSTAL-STRUCTURES OF [AG(PPZ)(2)](BF4) AND [AG(PYZ)(2)](PF6) (PPZ=PIPERAZINE, PYZ=PYRAZINE)

被引：100

作者：

CARLUCCI, L

CIANI, G

PROSERPIO, DM

SIRONI, A

机构：

[1] UNIV MILAN, DIPARTIMENTO CHIM STRUTTURALE & STEREOCHIM, I-20133 MILAN, ITALY

[2] UNIV MILAN, CTR CNR, I-20133 MILAN, ITALY

来源：

INORGANIC CHEMISTRY | 1995年 / 34卷 / 22期

关键词：

D O I：

10.1021/ic00126a048

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two novel silver(I) coordination polymers, [Ag(ppz)(2)](BF4) (1) and [Ag(pyz)(2)](PF6) (2) (ppz = piperazine, pyz = pyrazine), are prepared. Their crystal structures are found to contain markedly undulated 2D networks of distorted squares of Ag+ cations, in tetrahedral (1) and disphenoidal coordination geometries (2).

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页码：5698 / +

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