DIRECT OBSERVATION OF CORRELATION BETWEEN ELECTRON-EMISSION AND FRAGMENTATION INTO IONS FOLLOWING B-1S EXCITATION OF THE BF3 MOLECULE

被引：39

作者：

UEDA, K

OHMORI, K

OKUNISHI, M

CHIBA, H

SHIMIZU, Y

SATO, Y

HAYAISHI, T

SHIGEMASA, E

YAGISHITA, A

机构：

[1] UNIV TSUKUBA, INST APPL PHYS, TSUKUBA, IBARAKI 305, JAPAN

[2] NATL LAB HIGH ENERGY PHYS, PHOTON FACTORY, TSUKUBA, IBARAKI 305, JAPAN

来源：

PHYSICAL REVIEW A | 1995年 / 52卷 / 03期

关键词：

D O I：

10.1103/PhysRevA.52.R1815

中图分类号：

O43 [光学];

学科分类号：

070207 ; 0803 ;

摘要：

An alternative technique of coincidence between energy-selected electrons and mass- and energy-selected photoions, combined with angle-resolved photoion spectroscopy, has been applied to investigate the state-selected dissociation dynamics of the B 1s core-excited BF3 molecule. Dissociation from the spectator Auger final states both above and below the double-ionization threshold produces energetic B+ in the secondary processes of stepwise dissociation after the molecular deformation (D-3h-->C-3 nu, in marked contrast to dissociation following B 1s ionization in which energetic F+ is ejected within the D-3h plane of the parent BF3 molecule.

引用

页码：R1815 / R1818

页数：4

共 24 条

[21] The collisional behaviour of Ba[6s5d(D-3(J))] with CH3Cl investigated by time-resolved atomic emission and molecular chemiluminescence BaCl(A(2)Pi(1/2,3/2),B-2 Sigma(+)->X(2)Sigma(+)) following the pulsed dye-laser excitation of atomic barium
Husain, D
Lei, J
Castano, F
Rayo, MNS
LASER CHEMISTRY, 1997, 17 (01) : 53 - 71
[22] Investigation of Branching Ratios into BaI(A2cap pi1/2.3/2,B2a+) from the Reaction of Ba[6s5d(3DJ)] with CH3I by Time-resolved Atomic Emission and Molecular Chemiluminescence Following Pulsed Dye-Laser Excitation of Atomic Barium
Husain, D.
Lei, J.
Casta QQ o, F.
Sanchez Rayo, M. N.
Zeitschrift fuer Physikalische Chemie, 203 (1-2):
[23] Branching ratios for the production of the electronic states BaBr(A(2)Pi(1/2,3/2), B-2 Sigma(+)) from the reaction of Ba[6s5d(D-3(J))] with CH3Br investigated by time-resolved atomic emission and molecular chemiluminescence following pulsed dye laser excitation of atomic barium
Husain, D
Lei, J
Castano, F
Rayo, MNS
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 1997, 107 (1-3) : 1 - 8
[24] KINETIC INVESTIGATION OF (A) THE COLLISIONAL QUENCHING OF MG(33PJ) BY CO2 OVER THE TEMPERATURE-RANGE 600-1100-K BY TIME-RESOLVED ATOMIC EMISSION (MG(33P1)-]MG(31S0) + HV) AND (B), E - (E,V) TRANSFER FROM MG(33PJ) TO MGO BY TIME-RESOLVED MOLECULAR-EMISSION (MGO, B1SIGMA+ - A1PI AND B1SIGMA+ - X1SIGMA+) FOLLOWING PULSED DYE-LASER EXCITATION AT LAMBDA=457.1NM (MG(33P1)[-MG(31S0))3
HUSAIN, D
ROBERTS, G
BERICHTE DER BUNSEN-GESELLSCHAFT-PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 1986, 90 (04): : 360 - 369

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