THE SYNTHESIS OF ALPHA-ACETOXY SULFIDES AND THEIR LEWIS ACID-MEDIATED REACTIONS

被引：11
|
作者：
KRAUS, GA
MAEDA, H
机构：
[1] Department of Chemistry, Iowa State University, Ames
来源：
TETRAHEDRON LETTERS | 1995年 / 36卷 / 15期
关键词：
MERCURIC ACETATE; SULFIDE; LEWIS ACID; SILANE;
D O I：
10.1016/0040-4039(95)00349-H
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
alpha-Acetoxy sulfides can be conveniently prepared by the reaction of dithioacetals with mercuric acetate at ambient temperature. They react with allyltrimethylsilane, enol silyl ethers, and cyanotrimethylsilane in the presence of SnCl4 to afford butenyl sulfides, gamma-keto sulfides and alpha-cyano sulfides, respectively.
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页码：2599 / 2602
页数：4
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