NEUTRON-DIFFRACTION STUDY OF THE BORIDE Y(FE11.04TI0.52B0.43)TI-0.39 - A NEW PHASE OF A THMN12-TYPE INTERMETALLIC INTERSTITIAL COMPOUND

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作者
ZHANG, D [1 ]
ZHANG, ZD [1 ]
CHUANG, YC [1 ]
ZHANG, BS [1 ]
YANG, JL [1 ]
DU, HL [1 ]
机构
[1] INST ATOM ENERGY, BEIJING 102413, PEOPLES R CHINA
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中图分类号
O469 [凝聚态物理学];
学科分类号
070205 ;
摘要
A sample with nominal composition YFe10.5TiB0.5 has been prepared through careful processing. X-ray diffraction analysis revealed that the main phase in the sample is in the tetragonal ThMn12-type structure (space group, I4/mmm),-and a small amount (less than 3%) of alpha-Fe exists as a second phase. Neutron diffraction measurements indicated that, in the tetragonal structure, the boron atoms occupy the 8i sites, substituting for a few Ti atoms, while the substituted Ti atoms enter the interstitial 2b sites. The real composition of the main phase was determined to be Y(Fe11.04Ti0.52B0.43)Ti-0.39.
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页码:2587 / 2592
页数:6
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