A CONVENIENT ROUTE TO A NEW BICYCLOBUTANE MONOMER - ISOPROPYL 1-BICYCLOBUTANECARBOXYLATE

被引:10
作者
DRUJON, X [1 ]
HALL, HK [1 ]
机构
[1] UNIV ARIZONA,DEPT CHEM,CS MARVEL LABS,TUCSON,AZ 85721
关键词
D O I
10.1007/BF00297315
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Isopropyl 1-bicyclobutanecarboxylate was prepared over 5 steps in 24% overall yield from readily available materials. This monomer was highly reactive toward radical polymerization, and gave good yields of high polymers. © 1990 Springer-Verlag.
引用
收藏
页码:181 / 185
页数:5
相关论文
共 6 条
[1]   SYNTHESIS AND POLYMERIZATION OF 1-BICYCLOBUTANECARBONITRILES [J].
HALL, HK ;
BLANCHAR.EP ;
CHERKOFS.SC ;
SIEJA, JB ;
SHEPPARD, WA .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1971, 93 (01) :110-&
[2]  
HALL HK, 1976, J POLYM SCI MACROMOL, V2, P1
[3]   CROWN ETHER CATALYSIS OF DECARBOXYLATION AND DECARBALKOXYLATION OF BETA-KETO ACIDS AND MALONATES - A SYNTHETIC APPLICATION [J].
HUNTER, DH ;
PATEL, V ;
PERRY, RA .
CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1980, 58 (21) :2271-2277
[4]   CONVENIENT ROUTE TO 1,3-DISUBSTITUTED CYCLOBUTANES - AN INEXPENSIVE SYNTHESIS OF 3-OXOCYCLOBUTANECARBOXYLIC ACID [J].
PIGOU, PE ;
SCHIESSER, CH .
JOURNAL OF ORGANIC CHEMISTRY, 1988, 53 (16) :3841-3843
[5]   FREE-RADICAL POLYMERIZATION OF BICYCLOBUTANES [J].
SWARTZ, TD ;
HALL, HK .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1971, 93 (01) :137-&
[6]   BICYCLO[1.1.0]BUTANE [J].
WIBERG, KB ;
LAMPMAN, GM ;
CIULA, RP ;
CONNOR, DS ;
SCHERTLE.P ;
LAVANISH, J .
TETRAHEDRON, 1965, 21 (10) :2749-&