TRANSITION-METAL ION COMPLEXES OF THIOSEMICARBAZONES DERIVED FROM 2-ACETYLPYRIDINE N-OXIDE .4. IRON(III) AND COPPER(II) COMPLEXES OF THE 4N-ETHYLTHIOSEMICARBAZONES AND 4N-DIETHYLTHIOSEMICARBAZONES

被引：11
作者：
WEST, DX
BOROWY, LD
机构：
[1] Department of Chemistry, Illinois State University, Normal, 61761, IL
来源：
TRANSITION METAL CHEMISTRY | 1991年 / 16卷 / 01期
关键词：
D O I：
10.1007/BF01127860
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Copper(II) and iron(III) complexes of 2-acetylpyridine N-oxide N4-ethyl- and N4-diethylthiosemicarbazones have been prepared and characterized by physical and spectral methods. The N4-ethyl-derivative coordinates as a neutral, bidentate ligand with copper(II), and the N4-diethyl- as an anionic, tridentate ligand with both copper(II) and iron(III). The former ligand forms a mixed ligand complex (i.e., one neutral and one anionic ligand) with iron(III).
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页码：5 / 8
页数：4
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