UNSYMMETRICALLY DISUBSTITUTED FERROCENES .4. SYNTHESIS AND REACTIVITY OF 2-(NN-DIMETHYLAMINOMETHYL)FERROCENEBORNONIC ACID

被引：47

作者：

MARR, G

MOORE, RE

ROCKETT, BW

机构：

[1] Department of Applied Science, Wolverhampton College of Technology, Wolverhampton

来源：

JOURNAL OF THE CHEMICAL SOCIETY C-ORGANIC | 1968年 / 01期

关键词：

D O I：

10.1039/j39680000024

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The reaction of lithiated (NN-dimethylaminomethyl)ferrocene with tri-n-butyl borate has given [2-(NN-dimethylaminomethyl)ferroceneboronic acid. This amino-acid has been converted into the corresponding 2-chloro-, 2-bromo-, and 2-iodo-(dimethylaminomethyl)ferrocenes. The methiodides of these halo-amines underwent nucleophilic displacement reactions with amines, phenol, and aqueous sodium hydroxide to afford a variety of 2-halo-ferrocenes.

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页码：24 / &

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