Study of nanostructured polymeric composites used for organic light emitting diodes and organic solar cells

被引:1
作者
Do Ngoc Chung [1 ]
Nguyen Nang Dinh [1 ]
Tran Thi Thao [1 ]
Nguyen Phuong Hoai Nam [1 ]
Tran Quang Trung [2 ]
Hui, David [3 ]
机构
[1] Vietnam Natl Univ Hanoi, Univ Engn & Technol, 144 Xuan Thuy, Hanoi, Vietnam
[2] Vietnam Natl Univ, Coll Nat Sci, Ho Chi Minh City, Vietnam
[3] Univ New Orleans, Dept Mech Engn, New Orleans, LA 70148 USA
关键词
Nanocomposite; Organic Light Emitting Diodes (OLED); Organic Solar Cells (OSC); Current-Voltage (I-V) characteristic; Luminescence quenching;
D O I
10.1260/1708-5284.9.5.399
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Polymeric nanocomposite films from PEDOT and MEH-PPV embedded with surface modified TiO2 nanoparticles were prepared, respectively for the hole transport layer (HTL) and emission layer (EL) in Organic Light Emitting Diodes (OLED). The composite of MEH-PPV + nc-TiO2 was used for Organic Solar Cells (OCS). The results from the characterization of the properties of the nanocomposites and devices showed that electrical (I-V characteristics) and spectroscopic (photoluminescent) properties of the conjugate polymers were enhanced due to the incorporation of nc-TiO2 in the polymers. The OLEDs made from the nanocomposite films would exhibit a larger photonic efficiency and a longer lasting life. For the OSC made from MEH-PPV + nc-TiO2 composite, the fill factor (FF) reached a value as high as 0.34. Under illumination of light with a power density of 50 mW/cm(2), the photoelectrical conversion efficiency (PEC) was found to be of 0.15% corresponding to an open circuit voltage VOC = 1.15 V and a short-cut circuit current density JSC = 0.125 mA/cm(2).
引用
收藏
页码:399 / 405
页数:7
相关论文
共 15 条
[1]   Discrete hopping model of exciton transport in disordered media [J].
Burlakov, VM ;
Kawata, K ;
Assender, HE ;
Briggs, GAD ;
Ruseckas, A ;
Samuel, IDW .
PHYSICAL REVIEW B, 2005, 72 (07)
[2]   Enhanced luminance in polymer composite light emitting devices [J].
Carter, SA ;
Scott, JC ;
Brock, PJ .
APPLIED PHYSICS LETTERS, 1997, 71 (09) :1145-1147
[3]   Influence of metallic nanoparticles on the performance of organic electrophosphorescence devices [J].
Choulis, Stelios A. ;
Mathai, Mathew K. ;
Choong, Vi-En .
APPLIED PHYSICS LETTERS, 2006, 88 (21)
[4]  
Dinh Nguyen Nang, 2009, J APPL PHYS, V105
[5]   Hybrid nanorod-polymer solar cells [J].
Huynh, WU ;
Dittmer, JJ ;
Alivisatos, AP .
SCIENCE, 2002, 295 (5564) :2425-2427
[6]   The eta-solar cell with CuInS2:: A photovoltaic cell concept using an extremely thin absorber (eta) [J].
Kaiser, I ;
Ernst, K ;
Fischer, CH ;
Könenkamp, R ;
Rost, C ;
Sieber, I ;
Lux-Steiner, MC .
SOLAR ENERGY MATERIALS AND SOLAR CELLS, 2001, 67 (1-4) :89-96
[7]   Description of exciton transport in a TiO2/MEH-PPV heterojunction photovoltaic material [J].
Kawata, K ;
Burlakov, VM ;
Carey, MJ ;
Assender, HE ;
Briggs, GAD ;
Ruseckas, A ;
Samuel, IDW .
SOLAR ENERGY MATERIALS AND SOLAR CELLS, 2005, 87 (1-4) :715-724
[8]   Migration-assisted energy transfer at conjugated polymer/metal interfaces [J].
Markov, DE ;
Blom, PWM .
PHYSICAL REVIEW B, 2005, 72 (16)
[9]   A solid-state dye-sensitized solar cell fabricated with pressure-treated P25-TiO2 and CuSCN:: Analysis of pore filling and IV characteristics [J].
O'Regan, B ;
Lenzmann, F ;
Muis, R ;
Wienke, J .
CHEMISTRY OF MATERIALS, 2002, 14 (12) :5023-5029
[10]   On the mechanism of conductivity enhancement in poly (3,4-ethylenedioxythiophene): poly(styrene sulfonate) film through solvent treatment [J].
Ouyang, J ;
Xu, QF ;
Chu, CW ;
Yang, Y ;
Li, G ;
Shinar, J .
POLYMER, 2004, 45 (25) :8443-8450