AN IMPROVED METHOD FOR THE SYNTHESIS OF CATIONIC (ETA(5)-CYCLOPENTADIENYL) (ETA(3)-ALLYL)MO(CO)(NO) COMPLEXES - THE BENEFIT OF 1,2-DIMETHOXYETHANE AS A SOLVENT

被引：28
作者：
COSFORD, NDP [1 ]
LIEBESKIND, LS [1 ]
机构：
[1] EMORY UNIV,DEPT CHEM,ATLANTA,GA 30322
来源：
ORGANOMETALLICS | 1994年 / 13卷 / 04期
关键词：
D O I：
10.1021/om00016a059
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
In contrast to suggestions in the literature that ether solvents are incompatible with nitrosonium salts, treatment of (eta3-allyl)(eta5-cyclopentadienyl)dicarbonylmolybdenum complexes with solid NOPF6 in 1,2-dimethoxyethane at -10-degrees-C produces analytically pure [(eta3-allyl)carbonyl(eta5-cyclopentadienyl)nitrosylmolybdenum][PF6] as yellow solids.
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页码：1498 / 1503
页数：6
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