SYNTHESIS, CHARACTERIZATION AND X-RAY CRYSTAL-STRUCTURE OF CIS-TETRAKIS(ISOTHIOCYANATO)(TRIPHENYLPHOSPHINE)(TRIPHENYLPHOSPHINE OXIDE)RHENIUM(IV), [RE(NCS)4(PH3P)(PH3PO)]

被引：19

作者：

HUBENER, R ^{[1
]}

ABRAM, U ^{[1
]}

机构：

[1] UNIV TUBINGEN,INST INORGAN CHEM,MORGENSTELLE 18,D-72076 TUBINGEN,GERMANY

来源：

INORGANICA CHIMICA ACTA | 1993年 / 211卷 / 01期

关键词：

D O I：

10.1016/S0020-1693(00)82853-4

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

cis-Tetrakis(isothiocyanato)(triphenylphosphine)(triphenyl-phosphine oxide)rhenium(IV), [Re(NCS)4(Ph3P)(Ph3PO)], is formed during the reaction of [ReOCl3(Ph3P)2] and trimethylsilylisotbiocyanate, Me3SiNCS. The compound crystallizes monoclinic in the space group P2(1)/n, a=9.981(3), b=37.447(6), c=11.761(4) angstrom, beta=111.21(1)degrees and Z=4. Structure refinement converged at R=0.037. Pb3P and Ph3PO are cis-coordinated with Re-P and Re-O distances of 2.511(3) and 2.018(7) angstrom, respectively. The NCS ligands are coordinated via nitrogen.

引用

页码：121 / 123

页数：3

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