SYNTHESIS, CHARACTERIZATION AND X-RAY CRYSTAL-STRUCTURE OF CIS-TETRAKIS(ISOTHIOCYANATO)(TRIPHENYLPHOSPHINE)(TRIPHENYLPHOSPHINE OXIDE)RHENIUM(IV), [RE(NCS)4(PH3P)(PH3PO)]

被引：19

作者：

HUBENER, R ^{[1
]}

ABRAM, U ^{[1
]}

机构：

[1] UNIV TUBINGEN,INST INORGAN CHEM,MORGENSTELLE 18,D-72076 TUBINGEN,GERMANY

来源：

INORGANICA CHIMICA ACTA | 1993年 / 211卷 / 01期

关键词：

D O I：

10.1016/S0020-1693(00)82853-4

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

cis-Tetrakis(isothiocyanato)(triphenylphosphine)(triphenyl-phosphine oxide)rhenium(IV), [Re(NCS)4(Ph3P)(Ph3PO)], is formed during the reaction of [ReOCl3(Ph3P)2] and trimethylsilylisotbiocyanate, Me3SiNCS. The compound crystallizes monoclinic in the space group P2(1)/n, a=9.981(3), b=37.447(6), c=11.761(4) angstrom, beta=111.21(1)degrees and Z=4. Structure refinement converged at R=0.037. Pb3P and Ph3PO are cis-coordinated with Re-P and Re-O distances of 2.511(3) and 2.018(7) angstrom, respectively. The NCS ligands are coordinated via nitrogen.

引用

页码：121 / 123

页数：3

共 50 条

[21] MOLECULAR AND CRYSTAL-STRUCTURES OF [(PH3P)2N] [B3H7(NCS)] AND [(PH3P)2N] [B3H7(NCSE)] - THE NEED FOR LOW-TEMPERATURE X-RAY CRYSTALLOGRAPHY
ANDREWS, SJ
WELCH, AJ
INORGANICA CHIMICA ACTA-ARTICLES AND LETTERS, 1984, 88 (02): : 153 - 160
[22] Formation and X-ray crystal structure determination of the novel triplatinum cluster [(Ph3P)Pt(μ-SiC12H8)]3 from reaction of silafluorene with (Ph3P)2Pt(η2-C2H4)
Braddock-Wilking, J
Corey, JY
Dill, K
Rath, NP
ORGANOMETALLICS, 2002, 21 (25) : 5467 - 5469
[23] THE SYNTHESIS AND CHARACTERIZATION OF A CATIONIC TECHNETIUM(V) PHENYLIMIDO COMPLEX - THE X-RAY CRYSTAL-STRUCTURE OF [TCCL2(NPH)(PME(2)PH)(3)](BPH(4))
NICHOLSON, T
DAVISON, A
ZUBIETA, JA
CHEN, Q
JONES, AG
INORGANICA CHIMICA ACTA, 1995, 230 (1-2) : 205 - 208
[24] A HIGHLY STRAINED HETEROCYCLOSILOXANE - SYNTHESIS AND X-RAY CRYSTAL-STRUCTURE OF PENTAPHENYLBORACYCLOTRISILOXANE BSI2O3PH5
FOUCHER, DA
LOUGH, AJ
MANNERS, I
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1991, 414 (01) : C1 - C4
[25] TETRAPHENYLCYCLOPENTADIENONE COMPLEXES OF MOLYBDENUM - X-RAY CRYSTAL-STRUCTURE OF [MO(CO)3(C4PH4CO)]2
BEDDOES, RL
COOK, ES
MORRIS, MJ
POLYHEDRON, 1989, 8 (13-14) : 1810 - 1813
[26] SYNTHESIS OF PHENYLNITRENE COMPLEXES WITH N-TRIMETHYLSILYLANILINE .2. CHARACTERIZATION AND CRYSTAL-STRUCTURE OF THE RHENIUM(V) COMPLEXES MER-[RE(NPH)CL-3(NH(2)PH)(PH(3)P)] AND TRANS-[RE(NPH)(OME)CL-2(PH(3)P)(2)]
WITTERN, U
STRAHLE, J
ABRAM, U
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1995, 621 (08): : 1338 - 1343
[27] Synthesis and characterization of rhenium-copper complexes [(Ph3P)2N][Re3(CuX)(μ3-S)4Cl6(PMe2Ph)3] sulfide cluster (X = Cl, Br, I)
Iijima, K
Sunaga, T
Hirose, M
Saito, T
INORGANIC CHEMISTRY, 2006, 45 (08) : 3452 - 3455
[28] FORMATION OF AN UNUSUAL POLYMERIC 24-MEMBERED MACROCYCLIC COMPLEX OF PRASEODYMIUM(III) - X-RAY CRYSTAL-STRUCTURE OF [PR(PH3PAUL)2(NO3)3]N(L = SUCCINIMIDE ANION) AND OF ITS (PH3P)AUL PRECURSOR
GOODGAME, DML
OMAHONEY, CA
PLANK, SD
WILLIAMS, DJ
POLYHEDRON, 1993, 12 (22) : 2705 - 2710
[29] SYNTHESIS AND X-RAY CRYSTAL-STRUCTURE OF 2-BETA-D-RIBOFURANOSYLTHIAZOLE-4-CARBOXAMIDE-N3-OXIDE
DALLEY, NK
PETRIE, CR
REVANKAR, GR
ROBINS, RK
NUCLEOSIDES & NUCLEOTIDES, 1985, 4 (05): : 651 - 659
[30] SYNTHESIS AND X-RAY CRYSTAL-STRUCTURE OF COMPLEXES CP(CO)(2)MNP(SR)(3) (R=PR-I, PH)
SINYASHIN, OG
GORSHUNOV, IY
MILUKOV, VA
BATYEVA, ES
LITVINOV, IA
KATAEVA, ON
GINZBURG, AG
SOKOLOV, VI
RUSSIAN CHEMICAL BULLETIN, 1994, 43 (06) : 1054 - 1057

← 1 2 3 4 5 →