NMR-STUDIES OF THE ELECTRONIC-STRUCTURE OF LOW-SPIN IRON(III) PHOSPHONITE COMPLEXES - UNUSUAL (D(XZR)D(YZ))(4)(D(XY))(1) CONFIGURATION

被引：23

作者：

GUILLEMOT, M ^{[1
]}

SIMONNEAUX, G ^{[1
]}

机构：

[1] UNIV RENNES 1,CHIM ORGANOMET & BIOL LAB,CNRS,UA 415,F-35042 RENNES,FRANCE

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1995年 / 20期

关键词：

D O I：

10.1039/c39950002093

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Complexation of dimethylphenylphosphonite to (5,10,15,20-tetraphenylporphyrinato)iron(III) yields a low-spin derivative [Fe(tpp){P(OMe)(2)Ph}(2)]ClO4, showing NMR and EPR properties consistent with an iron(III) ion in the unusual ground-state configuration (d(xz),d(yz))(4) (d(xy))(1).

引用

页码：2093 / 2094

页数：2

共 44 条

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