NMR-STUDIES OF THE ELECTRONIC-STRUCTURE OF LOW-SPIN IRON(III) PHOSPHONITE COMPLEXES - UNUSUAL (D(XZR)D(YZ))(4)(D(XY))(1) CONFIGURATION

被引：23

作者：

GUILLEMOT, M ^{[1
]}

SIMONNEAUX, G ^{[1
]}

机构：

[1] UNIV RENNES 1,CHIM ORGANOMET & BIOL LAB,CNRS,UA 415,F-35042 RENNES,FRANCE

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1995年 / 20期

关键词：

D O I：

10.1039/c39950002093

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Complexation of dimethylphenylphosphonite to (5,10,15,20-tetraphenylporphyrinato)iron(III) yields a low-spin derivative [Fe(tpp){P(OMe)(2)Ph}(2)]ClO4, showing NMR and EPR properties consistent with an iron(III) ion in the unusual ground-state configuration (d(xz),d(yz))(4) (d(xy))(1).

引用

页码：2093 / 2094

页数：2

共 44 条

[1] 1H NMR and EPR studies of the electronic structure of low-spin iron(III) phosphonite mesotetraphenylchlorin complexes:: a (dxz,dyz)4(dxy)1 configuration from 293 to 4 K
Kobeissi, M
Simonneaux, G
INORGANICA CHIMICA ACTA, 2003, 343 : 18 - 26
[2] pi-Acid ligands in iron(III) porphyrinates. Characterization of low-spin bis(tert-butylisocyanide)(porphyrinato)iron(III) complexes having (d(xz),d(yz))(4)(d(xy))(1) ground states
Walker, FA
Nasri, H
TurowskaTyrk, I
Mohanrao, K
Watson, CT
Shokhirev, NV
Debrunner, PG
Scheidt, WR
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1996, 118 (48) : 12109 - 12118
[3] Low-temperature MCD studies of low-spin ferric complexes of tetramesitylporphyrinate: Evidence for the novel (d(xz),d(yz))(4)(d(xy))(1) ground state which models the spectroscopic properties of heme d
Cheesman, MR
Walker, FA
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1996, 118 (31) : 7373 - 7380
[4] 13C NMR studies of the electronic structure of low-spin iron(III) tetraphenylchlorin complexes
Ikezaki, Akira
Nakamura, Mikio
Juillard, Sandrine
Simonneaux, Gerard
INORGANIC CHEMISTRY, 2006, 45 (17) : 6728 - 6739
[5] 1H-NMR and EPR studies of the electronic structure of low-spin ruthenium(III) isocyanide porphyrin complexes:: unusual (dxz,dyz)4 (dxy,)1 configuration
Galardon, E
Le Maux, P
Paul, C
Poriel, C
Simonneaux, G
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2001, 629 (1-2) : 145 - 152
[6] 1-D and 2-D paramagnetic NMR of non-planar low-spin iron(III) porphyrin complexes.
Ogura, H
Walker, FA
Medforth, CJ
Smith, KM
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1997, 213 : 497 - INOR
[7] NMR studies to investigate the electronic structure of low-spin iron(III) porphyrins.
Stiles, P
Skidmore, K
Simonis, U
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2000, 219 : U855 - U855
[8] Enhanced VCD of low-spin d5 iron (III) complexes
Chin, Carolynn M.
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2006, 231
[9] 1H NMR and EPR studies of the electronic structure of low-spin iron(III) isocyanide mesotetraphenylchlorin complexes:: a (dxz,dyz)4(dxy)1 configuration from 293 to 4 K
Simonneaux, G
Kobeissi, M
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 2001, (10): : 1587 - 1592
[10] PROTON NMR-STUDIES OF THE ELECTRONIC AND MOLECULAR-STRUCTURE OF FERRIC LOW-SPIN HORSERADISH-PEROXIDASE COMPLEXES
DEROPP, JS
LAMAR, GN
SMITH, KM
LANGRY, KC
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1984, 106 (16) : 4438 - 4444

← 1 2 3 4 5 →