SYNTHESES, STRUCTURES, AND REACTIVITIES OF TERMINAL SELENIDO COMPLEXES OF TUNGSTEN

被引：13
|
作者：
RABINOVICH, D [1 ]
PARKIN, G [1 ]
机构：
[1] COLUMBIA UNIV,DEPT CHEM,NEW YORK,NY 10027
来源：
INORGANIC CHEMISTRY | 1994年 / 33卷 / 11期
关键词：
D O I：
10.1021/ic00089a001
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The terminal selenido complexes W(PMe3)4(Se)H2 and trans-W(PMe3)4(Se)2 are formed sequentially by the reaction of W(PMe3)4(eta2-CH2PMe2)H with H2Se. Dissociation of PMe3 from W(PMe3)4(Se)2 is facile, and treatment with Bu(t)NC and aldehydes yields the derivatives trans,trans,trans-W(PMe3)2-(CNBu(t))2(Se)2 and W(PMe3)2(Se)2(eta2-OCHR) (R = H, Ph), respectively. The series of terminal selenido complexes have been studied by X-ray diffraction and Se-77 NMR spectroscopy.
引用
收藏
页码：2313 / 2314
页数：2
相关论文
共 50 条
  • [21] Syntheses, structures, and reactivities of cobalt(III)-alkylperoxo complexes and their role in stoichiometric and catalytic oxidation of hydrocarbons
    Chavez, FA
    Rowland, JM
    Olmstead, MM
    Mascharak, PK
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1998, 120 (35) : 9015 - 9027
  • [22] Syntheses, structures, and reactivities of mono- and dinuclear iridium thiolato complexes containing nitrosyl ligands
    Matsukawa, S
    Kuwata, S
    Hidai, M
    INORGANIC CHEMISTRY, 2000, 39 (04) : 791 - 798
  • [23] Syntheses, structures, and reactions of η6 complexes of iridathiabenzene with chromium, molybdenum, and tungsten carbonyls
    Chen, JB
    Young, VG
    Angelici, RJ
    ORGANOMETALLICS, 2002, 21 (26) : 5951 - 5961
  • [24] Syntheses and molecular structures of new calix[4]arene molybdenum and tungsten complexes
    Attner, J
    Radius, U
    CHEMISTRY-A EUROPEAN JOURNAL, 2001, 7 (04) : 783 - 790
  • [25] Syntheses and crystal structures of tungsten complexes containing various (thiazoliumyl)diphenylphosphine ligands
    Yih, KH
    Yeh, SC
    Lin, YC
    Lee, GH
    Wang, Y
    ORGANOMETALLICS, 1998, 17 (04) : 513 - 518
  • [26] SYNTHESES, STRUCTURES AND SPECTRA OF BIS-(ALKLYIDYNYL TUNGSTEN) AND TRIS-(ALKYLIDYNYL TUNGSTEN) ARENE COMPLEXES
    STEVENSON, MA
    GEIB, SJ
    HOPKINS, MD
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1995, 210 : 131 - INOR
  • [27] Syntheses and reactivities of azido coordinated CpCo(dithiolene) complexes
    Nomura, Mitsushiro
    Sakamoto, Noriko
    Nakajima, Hirokazu
    Fujita-Takayama, Chikako
    Sugiyama, Toru
    Kajitani, Masatsugu
    POLYHEDRON, 2011, 30 (17) : 2890 - 2895
  • [28] SYNTHESIS AND REACTIVITIES OF TUNGSTEN COMPLEXES WITH DISUBSTITUTED TRIMETHYLENEMETHANE LIGANDS
    WU, IY
    CHENG, MC
    LIN, YC
    WANG, Y
    ORGANOMETALLICS, 1993, 12 (05) : 1686 - 1693
  • [29] Syntheses, structures, and reactivities of sulfur-containing cycloalkenes
    Shimizu, T
    Iwata, K
    Murakami, H
    Kamigata, N
    PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 1997, 120 : 457 - 458
  • [30] Syntheses, structures, and reactivities of heteroleptic magnesium amide thiolates
    Teng, WJ
    Englich, U
    Ruhlandt-Senge, K
    INORGANIC CHEMISTRY, 2000, 39 (17) : 3875 - 3880
12345