SYNTHESES, STRUCTURES, AND REACTIVITIES OF TERMINAL SELENIDO COMPLEXES OF TUNGSTEN

被引：13

作者：

RABINOVICH, D ^{[1
]}

PARKIN, G ^{[1
]}

机构：

[1] COLUMBIA UNIV,DEPT CHEM,NEW YORK,NY 10027

来源：

INORGANIC CHEMISTRY | 1994年 / 33卷 / 11期

关键词：

D O I：

10.1021/ic00089a001

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The terminal selenido complexes W(PMe3)4(Se)H2 and trans-W(PMe3)4(Se)2 are formed sequentially by the reaction of W(PMe3)4(eta2-CH2PMe2)H with H2Se. Dissociation of PMe3 from W(PMe3)4(Se)2 is facile, and treatment with Bu(t)NC and aldehydes yields the derivatives trans,trans,trans-W(PMe3)2-(CNBu(t))2(Se)2 and W(PMe3)2(Se)2(eta2-OCHR) (R = H, Ph), respectively. The series of terminal selenido complexes have been studied by X-ray diffraction and Se-77 NMR spectroscopy.

引用

页码：2313 / 2314

页数：2

共 50 条

[1] THE SYNTHESES, STRUCTURES, AND REACTIVITY OF TERMINAL SELENIDO COMPLEXES OF TUNGSTEN
RABINOVICH, D
PARKIN, G
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1994, 208 : 194 - INOR
[2] SYNTHESES, REACTIVITIES AND MOLECULAR-STRUCTURES OF TUNGSTEN COMPLEXES CONTAINING THE DIPHENYLPHOSPHINODITHIOFORMATO LIGAND
YIH, KH
LIN, YC
CHENG, MC
WANG, Y
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1995, (08): : 1305 - 1313
[3] SYNTHESES, STRUCTURES, AND REACTIVITIES OF NOVEL COPPER(II) COMPLEXES
MALACHOWSKI, MR
DAVIDSON, MG
HOFFMAN, JN
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1988, 195 : 321 - INOR
[4] Syntheses and structures of selenido dimanganese and iron-manganese carbonyl cluster complexes
Adams, RD
Kwon, OS
Sanyal, S
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2003, 681 (1-2) : 258 - 263
[5] Syntheses and Structures of Terminal Arylalumylene Complexes
Nagata, Koichi
Agou, Tomohiro
Tokitoh, Norihiro
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2014, 53 (15) : 3881 - 3884
[6] TERMINAL SULFIDE AND SELENIDO COMPLEXES OF TIN - SYNTHESES AND STRUCTURES OF [ETA(4)-ME(8)TAA]SNE (E=S, SE)
KUCHTA, MC
PARKIN, G
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1994, 116 (18) : 8372 - 8373
[7] Syntheses, Structures, and Reactivities of Novel Palladium β-Diiminato-Acetate Complexes
Hadzovic, Alen
Song, Datong
INORGANIC CHEMISTRY, 2008, 47 (24) : 12010 - 12017
[8] Syntheses, structures and reactivities of Co(III)-alkylperoxo complexes and their role in oxidation of hydrocarbons
Chavez, FA
Olmstead, MM
Mascharak, PK
JOURNAL OF INORGANIC BIOCHEMISTRY, 1999, 74 (1-4) : 93 - 93
[9] Syntheses, structures and reactivities of diindenyl-coordinated diiron bridging carbene complexes
Zhang, Lei
Sun, Jie
Zhu, Huping
Xu, Qiang
Tsumori, Nobuko
Chen, Jiabi
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2006, 691 (22) : 4641 - 4651
[10] Syntheses, structures, and properties of novel molybdenum and tungsten complexes of fullerenes
Tang, KL
Jin, XL
Tang, YQ
PHYSICS OF THE SOLID STATE, 2002, 44 (04) : 612 - 614

← 1 2 3 4 5 →