LARGE CLUSTERS OF METAL-IONS - THE TRANSITION FROM MOLECULAR TO BULK MAGNETS

被引：792
作者：
GATTESCHI, D [1 ]
CANESCHI, A [1 ]
PARDI, L [1 ]
SESSOLI, R [1 ]
机构：
[1] CENS,LAB LEON BRILLOUIN,F-91191 GIF SUR YVETTE,FRANCE
来源：
SCIENCE | 1994年 / 265卷 / 5175期
关键词：
D O I：
10.1126/science.265.5175.1054
中图分类号：
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号：
07 ; 0710 ; 09 ;
摘要：
Clusters of metal ions are a class of compounds actively investigated for their magnetic properties, which should gradually change from those of simple paramagnets to those of bulk magnets. However, their interest lies in a number of different disciplines: chemistry, which seeks new synthetic strategies to make larger and larger clusters in a controlled manner; physics, which can test the validity of quantum mechanical approaches at the nanometer scale; and biology, which can use them as models of biomineralization of magnetic particles.
引用
收藏
页码：1054 / 1058
页数：5
相关论文
共 45 条
  • [1] MACROSCOPIC QUANTUM EFFECTS IN NANOMETER-SCALE MAGNETS
    AWSCHALOM, DD
    DIVINCENZO, DP
    SMYTH, JF
    [J]. SCIENCE, 1992, 258 (5081) : 414 - 421
  • [2] MAGNETIC-PROPERTIES OF HIGH-NUCLEARITY SPIN CLUSTERS - 14-OXOVANADIUM(IV) AND 15-OXOVANADIUM(IV) CLUSTERS
    BARRA, AL
    GATTESCHI, D
    PARDI, L
    MULLER, A
    DORING, J
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (22) : 8509 - 8514
  • [3] POTENTIAL BUILDING-BLOCKS FOR MOLECULAR FERROMAGNETS - [MN12O12(O2CPH)16(H2O)4] WITH A S=14 GROUND-STATE
    BOYD, PDW
    LI, QY
    VINCENT, JB
    FOLTING, K
    CHANG, HR
    STREIB, WE
    HUFFMAN, JC
    CHRISTOU, G
    HENDRICKSON, DN
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1988, 110 (25) : 8537 - 8539
  • [4] BRUS LE, 1989, J MATER RES, V4, P704
  • [5] PREPARATION, CRYSTAL-STRUCTURE, AND MAGNETIC-PROPERTIES OF AN OLIGONUCLEAR COMPLEX WITH 12 COUPLED SPINS AND AN S=12 GROUND-STATE
    CANESCHI, A
    GATTESCHI, D
    LAUGIER, J
    REY, P
    SESSOLI, R
    ZANCHINI, C
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1988, 110 (09) : 2795 - 2799
  • [6] ALTERNATING-CURRENT SUSCEPTIBILITY, HIGH-FIELD MAGNETIZATION, AND MILLIMETER BAND EPR EVIDENCE FOR A GROUND S = 10 STATE IN [MN12O12(CH3COO)16(H2O)4].2CH3COOH.4H2O
    CANESCHI, A
    GATTESCHI, D
    SESSOLI, R
    BARRA, AL
    BRUNEL, LC
    GUILLOT, M
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (15) : 5873 - 5874
  • [7] MAGNETIC-PROPERTIES OF AN OCTANUCLEAR IRON(III) CATION
    DELFS, C
    GATTESCHI, D
    PARDI, L
    SESSOLI, R
    WIEGHARDT, K
    HANKE, D
    [J]. INORGANIC CHEMISTRY, 1993, 32 (14) : 3099 - 3103
  • [8] FERRITIN - DESIGN AND FORMATION OF AN IRON-STORAGE MOLECULE
    FORD, GC
    HARRISON, PM
    RICE, DW
    SMITH, JMA
    TREFFRY, A
    WHITE, JL
    YARIV, J
    [J]. PHILOSOPHICAL TRANSACTIONS OF THE ROYAL SOCIETY B-BIOLOGICAL SCIENCES, 1984, 304 (1121) : 551 - +
  • [9] GATTESCHI D, 1993, GAZZ CHIM ITAL, V123, P231
  • [10] A DECANUCLEAR MIXED-VALENT MANGANESE COMPLEX WITH A HIGH-SPIN MULTIPLICITY IN THE GROUND-STATE
    GOLDBERG, DP
    CANESCHI, A
    LIPPARD, SJ
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1993, 115 (20) : 9299 - 9300
12345