SPECTROFLUOROMETRIC HYDRODYNAMIC VOLTAMMETRY - THEORY AND PRACTICE

被引：16
作者：
COMPTON, RG
FISHER, AC
WELLINGTON, RG
WINKLER, J
机构：
[1] Physical Chemistry Laboratory, Oxford University, Oxford OX1 3QZ, South Parks Road
来源：
JOURNAL OF PHYSICAL CHEMISTRY | 1992年 / 96卷 / 20期
关键词：
D O I：
10.1021/j100199a061
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
A flow cell for simultaneous spectrofluorimetric voltammetry is described. The relevant theory is presented and the sensitivity of the technique evaluated. Experiments involving (a) the photooxidation of bis(benzylidene)acenaphthene and (b) the oxidation of p-phenylenediamine are shown to be in good agreement with theory. It is demonstrated that the technique can reveal the existence of trace quantities of electrode reaction intermediates and products and show previously unsuspected species participating in the electrode process.
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页码：8153 / 8157
页数：5
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