VERSATILE SYNTHETIC METHOD FOR DIIRON BRIDGING ALLENYLIDENE COMPLEXES (ETA(5)-C(5)ME(5))(2)FE-2(MU-CO)(CO)(2)(MU-ETA(1)ETA(1)-C=C=CR(1)R(2)) VIA NUCLEOPHILIC-ADDITION TO THE ETHYNEDIYLDIIRON COMPLEX (MU-C-C)[FE(ETA(5)-C(5)ME(5))(CO)(2)](2)

被引：9

作者：

TERADA, M ^{[1
]}

MASAKI, Y ^{[1
]}

TANAKA, M ^{[1
]}

AKITA, M ^{[1
]}

MOROOKA, Y ^{[1
]}

机构：

[1] TOKYO INST TECHNOL,RESOURCES UTILIZAT RES LAB,MIDORI KU,YOKOHAMA,KANAGAWA 226,JAPAN

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1995年 / 16期

关键词：

D O I：

10.1039/c39950001611

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Addition of an excess amount of nucleophile (alkyllithium or LiHBEt(3)) to the ethynediyldiiron complex (eta(5)-C(5)Me(5))(CO)(2)Fe-C=C-Fe(eta(5)-C(5)Me(5))(CO)(2) 1 in portions, affords a variety of diiron bridging allenylidene complexes (eta(5)-C(5)Me(5))(2)Fe-2(mu-CO)(CO)(2)(mu-C=C=CR(1)R(2)) 2 (R(1), R(2) = H, Me, Bu, Ph) including the parent compound 2a (R(1) = R(2) = H).

引用

页码：1611 / 1612

页数：2

共 9 条

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