THE CRYSTAL AND MOLECULAR-STRUCTURE OF BIS(ETA-5-TRIMETHYLSILYLCYCLOPENTADIENYL)TITANIUM(IV) DICHLORIDE, TI(ETA-5-C5H4SIME3)2CL2

被引：13

作者：

KLOURAS, N

NASTOPOULOS, V

机构：

[1] Department of Chemistry, University of Patras, Patras

来源：

MONATSHEFTE FUR CHEMIE | 1991年 / 122卷 / 6-7期

关键词：

RING SUBSTITUTED TITANOCENES; MOLECULAR STRUCTURE; X-RAY ANALYSIS;

D O I：

10.1007/BF00809809

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The crystal and molecular structure of the titanocene complex Ti(eta-5-C5H4SiMe3)2Cl2 has been determined by X-ray diffraction studies. The compound crystallizes in the triclinic crystal system [a = 6.747(8), b = 12.815(2), c = 12.928(4) angstrom and alpha = 67.16(2), beta = 82.29(5), gamma = 74.83(4)-degrees] in the space group P 1BAR with 2 formula units in the unit cell. The coordination about the titanium atom formed by the two chlorine atoms and the centroids of the cyclopentadienyl rings is that of a distorted tetrahedron. The Cl-Ti-Cl angle is 91.63-degrees while the (centroid)-Ti-(centroid) angle is 131.02-degrees.

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页码：551 / 556

页数：6

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