REDUCTIVE CARBONYLATION OF ALKENES USING ZWITTERIONIC RHODIUM COMPLEXES AS CATALYSTS

被引：22

作者：

ZHOU, JQ ^{[1
]}

ALPER, H ^{[1
]}

机构：

[1] UNIV OTTAWA,DEPT CHEM,OTTAWA CARLETON CHEM INST,OTTAWA K1N 6N5,ONTARIO,CANADA

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1991年 / 04期

关键词：

D O I：

10.1039/c39910000233

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Alkenes react with carbon monoxide, sodium borohydride, propan-2-ol and a catalytic amount of Rh(cod)(eta-6-PhBPh3) (cod = cyclooctadiene) to give alcohols in fine yields; high regioselectivity for the branched or linear alcohol is usually observed, depending on the organic substrate.

引用

页码：233 / 234

页数：2

共 10 条

[1] ZWITTERIONIC RHODIUM COMPLEXES AS CATALYSTS FOR THE HYDROFORMYLATION OF OLEFINS [J].

AMER, I ;

ALPER, H .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1990, 112 (09) :3674-3676

[2]

CHALK AJ, 1988, FLAVOURS FRAGRANCES, P867

[3] HYDROFORMYLATION OF 1-HEXENE BY SOLUBLE AND ZEOLITE-SUPPORTED RHODIUM SPECIES .2. [J].

DAVIS, ME ;

SCHNITZER, J ;

ROSSIN, JA ;

TAYLOR, D ;

HANSON, BE .

JOURNAL OF MOLECULAR CATALYSIS, 1987, 39 (02) :243-259

[4] REACTIONS OF COMPOUNDS OF THE TYPE [(DIENE)RHX]2(DIENE = CYCLOOCTA-1,5-DIENE, BICYCLO[2.2.1]HEPTA-2,5-DIENE; X=CL, BR) WITH TERTIARY PHOSPHINES AND PHOSPHITES [J].

HAINES, LM .

INORGANIC CHEMISTRY, 1970, 9 (06) :1517-+

[5] HYDROFORMYLATION OF 1-HEXENE UTILIZING HOMOGENEOUS RHODIUM CATALYSTS - REGIOSELECTIVITY AS A FUNCTION OF CONVERSION [J].

HANSON, BE ;

DAVIS, ME .

JOURNAL OF CHEMICAL EDUCATION, 1987, 64 (11) :928-930

[6] DIRECT FORMATION OF ALCOHOLS IN HOMOGENEOUS HYDROFORMYLATION CATALYZED BY RHODIUM COMPLEXES [J].

MACDOUGALL, JK ;

COLEHAMILTON, DJ .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1990, (02) :165-167

[7] ALCOHOLS AS SOURCES OF HYDROGEN IN HYDROFORMYLATION OF ALKENES [J].

MACDOUGALL, JK ;

COLEHAMILTON, DJ .

POLYHEDRON, 1990, 9 (09) :1235-1236

[8] HYDROFORMYLATION - AN OLD YET NEW INDUSTRIAL ROUTE TO ALCOHOLS [J].

PRUETT, RL .

JOURNAL OF CHEMICAL EDUCATION, 1986, 63 (03) :196-198

[9]

SHIMIZU Y, 1988, Patent No. 233945

[10]

TAKAHASHI E, 1988, Patent No. 290837

← 1 →