A SIMPLE ROUTE TO SULFUR-BRIDGED ANNULENES

被引：99

作者：

HU, ZY ^{[1
]}

ATWOOD, JL ^{[1
]}

CAVA, MP ^{[1
]}

机构：

[1] UNIV ALABAMA,DEPT CHEM,TUSCALOOSA,AL 35487

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1994年 / 59卷 / 26期

关键词：

D O I：

10.1021/jo00105a025

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The McMurry coupling reaction of thiophene-derived dialdehydes has been employed as the key step in the synthesis of the sulfur-bridged annulenes 3, 4, 6-9, and 14. Dication 9 is the second example of a peripherally aromatic (26 pi) dication of this class, while the 22 pi annulene 14 is the first neutral aromatic annulene derived solely from thiophene.

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页码：8071 / 8075

页数：5

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