ELECTROCHEMICAL ADDITION OF CHLORODIFLUOROACETYL AROMATIC-COMPOUNDS TO ELECTRON-RICH OLEFINIC SUBSTRATES - A CONVENIENT SYNTHESIS OF GEM-DIFLUORO HETEROCYCLIC-COMPOUNDS

被引：18

作者：

MEDEBIELLE, M

机构：

[1] Laboratoire d'Electrochimie Moléculaire, l'Université Denis Diderot (Paris 7), Associée au CNRS, 75251 Paris Cedex 05

来源：

TETRAHEDRON LETTERS | 1995年 / 36卷 / 12期

关键词：

D O I：

10.1016/0040-4039(95)00222-X

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Indirect electrochemical reduction in acetonitrile of N,N-dimethyl-4-(chlorodifluoroacetyl)-1-napthylamine and of N,N-dimethyl-2,4-bis(chlorodifluoroacetyl)-1-napthylamine in the presence of electron-rich olefinic substrates yields gem-difluoro heterocyclic compounds after intramolecular cyclization of a gamma,gamma,-difluoroalkyl radical.

引用

页码：2071 / 2074

页数：4

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