STEPWISE SYNTHESES OF UNSYMMETRICAL TETRA-ARYLPORPHYRINS - ADAPTATION OF THE MACDONALD DIPYRROLE SELF-CONDENSATION METHODOLOGY

被引：25

作者：

WALLACE, DM ^{[1
]}

SMITH, KM ^{[1
]}

机构：

[1] UNIV CALIF DAVIS,DEPT CHEM,DAVIS,CA 95616

来源：

TETRAHEDRON LETTERS | 1990年 / 31卷 / 50期

关键词：

D O I：

10.1016/S0040-4039(00)88540-8

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A new synthetic route to meso-tetraarylporphyrins [e.g. (12,13)] using a MacDonald-type 2+2 condensation is established. The method presented here shows wide applicability for the preparation of 5,10,15,20-tetra-arylsubstituted porphyrins with two-fold rotational symmetry. The 2+2 method is further extended to give a tetraarylporphyrin (14) bearing four different aryl groups in a predesignated array. © 1990.

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页码：7265 / 7268

页数：4

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