KINETICS OF THE FORMATION, DECOMPOSITION, AND DISPROPORTIONATION REACTIONS OF N-CHLOROBUTYLAMINES

被引：18

作者：

ANTELO, JM

ARCE, F

CASTRO, MC

CRUGEIRAS, J

PEREZMOURE, JC

RODRIGUEZ, P

机构：

[1] Departamento de Química Física, Facultad de Química, Universidad de Santiago de Compostela

来源：

INTERNATIONAL JOURNAL OF CHEMICAL KINETICS | 1995年 / 27卷 / 07期

关键词：

D O I：

10.1002/kin.550270709

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The formation of N-chlorobutylamines is a reaction of order one with respect to hypochlorite and amine, and order -1 with respect to OH-. Kinetic studies show that N-chlorobutylamines undergo decomposition in basic aqueous media, and disproportionation (with formation of N,N-dichloramines) in acidic media, mechanisms are put forward for both these processes. (C) 1995 John Wiley and Sons, Inc.

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页码：703 / 717

页数：15

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