Poly(imide)/Organically-Modified Montmorillonite Nanocomposite as a Potential Membrane for Alkaline Fuel Cells

被引:5
作者
Battirola, Liliane C. [1 ]
Gasparotto, Luiz H. S. [1 ]
Rodrigues-Filho, Ubirajara P. [1 ]
Tremiliosi-Filho, Germano [1 ]
机构
[1] Univ Sao Paulo, Inst Quim Sao Carlos, BR-13560970 Sao Carlos, SP, Brazil
来源
MEMBRANES | 2012年 / 2卷 / 03期
基金
巴西圣保罗研究基金会;
关键词
clay-modified poly(imide); alkaline fuel cell; membranes;
D O I
10.3390/membranes2030430
中图分类号
Q5 [生物化学]; Q7 [分子生物学];
学科分类号
071010 ; 081704 ;
摘要
In this work we evaluated the potentiality of a poly(imide) (PI)/organically-modified montmorillonite (O-MMT) nanocomposite membrane for the use in alkaline fuel cells. Both X-ray diffraction and scanning electron microscopy revealed a good dispersion of O-MMT into the PI matrix and preservation of the O-MMT layered structure. When compared to the pure PI, the addition of O-MMT improved thermal stability and markedly increased the capability of absorbing electrolyte and ionic conductivity of the composite. The results show that the PI/O-MMT nanocomposite is a promising candidate for alkaline fuel cell applications.
引用
收藏
页码:430 / 439
页数:10
相关论文
共 26 条
[1]   Characterization and use of anionic membranes for alkaline fuel cells [J].
Agel, E ;
Bouet, J ;
Fauvarque, JF .
JOURNAL OF POWER SOURCES, 2001, 101 (02) :267-274
[2]   Alkaline direct alcohol fuel cells [J].
Antolini, E. ;
Gonzalez, E. R. .
JOURNAL OF POWER SOURCES, 2010, 195 (11) :3431-3450
[3]   The direct formate fuel cell with an alkaline anion exchange membrane [J].
Bartrom, Amy M. ;
Haan, John L. .
JOURNAL OF POWER SOURCES, 2012, 214 :68-74
[4]  
Biswas M, 2001, ADV POLYM SCI, V155, P167
[5]   New vistas in polymer degradation. Thermal oxidation processes in poly(ether imide) [J].
Carroccio, S ;
Puglisi, C ;
Montaudo, G .
MACROMOLECULES, 2005, 38 (16) :6849-6862
[6]   Synthesis and properties of fluorine-containing polybenzi.midazole/montmorillonite nanocomposite membranes for direct methanol fuel cell applications [J].
Chuang, Shih-Wei ;
Hsu, Steve Lien-Chung ;
Hsu, Chiao-Ling .
JOURNAL OF POWER SOURCES, 2007, 168 (01) :172-177
[7]   Polymeric materials as anion-exchange membranes for alkaline fuel cells [J].
Couture, Guillaume ;
Alaaeddine, Ali ;
Boschet, Frederic ;
Ameduri, Bruno .
PROGRESS IN POLYMER SCIENCE, 2011, 36 (11) :1521-1557
[8]  
Giannelis EP, 1998, APPL ORGANOMET CHEM, V12, P675, DOI 10.1002/(SICI)1099-0739(199810/11)12:10/11<675::AID-AOC779>3.0.CO
[9]  
2-V
[10]   Flammability properties of polymer - Layered-silicate nanocomposites. Polypropylene and polystyrene nanocomposites [J].
Gilman, JW ;
Jackson, CL ;
Morgan, AB ;
Harris, R ;
Manias, E ;
Giannelis, EP ;
Wuthenow, M ;
Hilton, D ;
Phillips, SH .
CHEMISTRY OF MATERIALS, 2000, 12 (07) :1866-1873