TRANSITION-METAL-PROMOTED RING-OPENING REACTIONS OF VINYLCYCLOPROPENES - 1,2,3,5-ETA-PENTA-2,4-DIENEDIYL AND 1,5-ETA-PENTA-2,4-DIENEDIYL (1-METALLACYCLOHEXA-2,4-DIENE) COMPLEXES OF RHODIUM(III) AND IRIDIUM(III) AND THEIR CONVERSION TO (ETA-5-CYCLOPENTADIENYL)HYDRIDOMETAL COMPOUNDS

被引：38

作者：

EGAN, JW

HUGHES, RP

RHEINGOLD, AL

机构：

[1] DARTMOUTH COLL,DEPT CHEM,HANOVER,NH 03755

[2] UNIV DELAWARE,DEPT CHEM,NEWARK,DE 19716

来源：

ORGANOMETALLICS | 1987年 / 6卷 / 07期

关键词：

D O I：

10.1021/om00150a034

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

引用

页码：1578 / 1581

页数：4

共 8 条

[1] PENTADIENYL-METAL-PHOSPHINE CHEMISTRY .12. SYNTHESIS, STRUCTURE, AND SPECTROSCOPY OF IRIDACYCLOHEXADIENE COMPLEXES [J].

BLEEKE, JR ;

PENG, WJ .

ORGANOMETALLICS, 1987, 6 (07) :1576-1578

[2]

CHO SH, UNPUB J ORG CHEM

[3] METALLACYCLOHEXATRIENES OR METALLABENZENES - SYNTHESIS OF OSMABENZENE DERIVATIVES AND X-RAY CRYSTAL-STRUCTURE OF [OS(CSCHCHCHCH)(CO)(PPH3)2] [J].

ELLIOTT, GP ;

ROPER, WR ;

WATERS, JM .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1982, (14) :811-813

[4] STEPWISE TRANSITION-METAL PROMOTED RING EXPANSION REACTIONS OF VINYLCYCLOPROPENES TO GIVE CYCLOPENTADIENES AND CYCLOHEXA-2,4-DIENONES - THE 1ST EXAMPLE OF A 1-METALLACYCLOHEXA-2,4-DIENE COMPLEX, ([PT-CH2-CH=C(PH)-C(PH)=C(PH)](PPH3)2) [J].

GRABOWSKI, NA ;

HUGHES, RP ;

JAYNES, BS ;

RHEINGOLD, AL .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1986, (23) :1694-1695

[5] SYNTHESIS OF TRIMETHYLPHOSPHINE COMPLEXES OF RHODIUM AND RUTHENIUM - X-RAY CRYSTAL-STRUCTURES OF TETRAKIS(TRIMETHYLPHOSPHINE)RHODIUM(I) CHLORIDE AND CHLOROTRIS(TRIMETHYLPHOSPHINE)RHODIUM(I) [J].

JONES, RA ;

REAL, FM ;

WILKINSON, G ;

GALAS, AMR ;

HURSTHOUSE, MB ;

MALIK, KMA .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1980, (03) :511-518

[6]

PADWA A, 1979, ORG PHOTOCHEM, V4, P261

[7]

THORN DL, 1979, NOUV J CHIM, V3, P39

[8] PHOTOCHEMICAL .143. DIRADICAL PATHWAYS IN VINYLCYCLOPROPENE TRIPLET REARRANGEMENTS - MECHANISTIC AND EXPLORATORY ORGANIC-PHOTOCHEMISTRY [J].

ZIMMERMAN, HE ;

FLEMING, SA .

JOURNAL OF ORGANIC CHEMISTRY, 1985, 50 (14) :2539-2551

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