THE VIBRATIONAL-SPECTRA OF COMPLEXES WITH PLANAR MONOTHIOOXAMIDES .3. THE PALLADIUM(II) COMPLEXES OF NEUTRAL MONOTHIOOXAMIDES

被引：4
作者：
MANESSIZOUPA, E
PERLEPES, SP
FABRETTI, AC
BELLAIHOU, M
DESSEYN, HO
机构：
[1] UNIV PATRAS,DEPT CHEM,PATRAI,GREECE
[2] UNIV MODENA,DEPT CHEM,I-41100 MODENA,ITALY
[3] RUCA,ANORGAN SCHEIKUNDE LAB,B-2020 ANTWERP,BELGIUM
来源：
SPECTROSCOPY LETTERS | 1994年 / 27卷 / 01期
关键词：
MONOTHIOOXAMIDES; PALLADIUM(II) COMPLEXES; LIGAND FIELD SPECTRA; INFRARED SPECTRA; RAMAN SPECTRA;
D O I：
10.1080/00387019408002511
中图分类号：
O433 [光谱学];
学科分类号：
0703 ; 070302 ;
摘要：
The new complexes trans-[PdX(2)(H(4)MTO)(2)] (X= Cl, Br, l), trans-[PdX(2)(H(3)MMTO)(2)] (X= Cl, Br, l), trans-[PdX(2)(SH3)(2)] (X= Cl, Br, l), [Pd(H(4)MTO)(4)]Cl-2 and [Pd(H(3)MMTO)(4)]Cl-2, where H(4)MTO= monothiooxamide, H(3)MMTO = N(o)-methylmonothiooxamide and SH3 = N(s)-methylmonothiooxamide, have been prepared. The complexes were characterized by elemental analyses, conductivity measurements, X-ray powder patterns, thermal methods and spectroscopic (UV/VIS, FT-IR, Laser-Raman) studies. The vibrational analysis of the complexes is given using NH/ND and CH3/CD3 isotopic substitutions. Monomeric square planar structures are assigned for the complexes in the solid state. The neutral monothiooxamides behave as monodentate ligands coordinating through their thioamide sulfur atom. The complex [Pd(SH2)(2)] was isolated during the thermal decomposition of trans - [PdCl2(SH3)(2)].
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页码：97 / 118
页数：22
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