INTERMOLECULAR INTERACTIONS IN BLENDS OF FUNCTIONALIZED PROPYLENE POLYMERS WITH POLY(VINYLCHLORIDE) OR POLYSTYRENE

被引:13
|
作者
BENEDETTI, E [1 ]
POSAR, F [1 ]
DALESSIO, A [1 ]
VERGAMINI, P [1 ]
AGLIETTO, M [1 ]
RUGGERI, G [1 ]
CIARDELLI, F [1 ]
机构
[1] UNIV PISA,IST CHIM ORGAN IND,I-56100 PISA,ITALY
来源
BRITISH POLYMER JOURNAL | 1985年 / 17卷 / 01期
关键词
COPOLYMERS - Spectroscopic Analysis - POLYOLEFINS - Spectroscopic Analysis;
D O I
10.1002/pi.4980170109
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Atactic and isotactic polypropylene (APP and IPP), and ethylene-propylene copolymers (EP), functionalized by reacting the molten polymer with diethylmaleate (DEM) in the presence of dicumylperoxide (DCP), have been blended with poly(vinylchloride) (PVC) and polystyrene (PS). These mixtures have been investigated by means of infrared spectroscopy at different compositions in the region of carbonyl absorption. The features of this last band in the mixture suggest the occurrence of intermolecular interactions involving mainly the carbonyl groups of the functionalized polymer and the methine hydrogens of PVC.
引用
收藏
页码:34 / 37
页数:4
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