SYNTHESIS OF OLIGOMERS WITH TRIPLE SIDE-CHAIN BONDS

被引:0
作者
MOROZOVA, LV
MIKHALEVA, AI
MARKOVA, MV
TROFIMOV, BA
机构
来源
VYSOKOMOLEKULYARNYE SOEDINENIYA SERIYA A & SERIYA B | 1993年 / 35卷 / 05期
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中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Ethylene glycol vinylpropargyl diether was synthesized via the reaction of ethylene glycol vinyl ether with propargyl chloride under conditions of interfacial catalysis. Selective polymerization of the monomer in the presence of iron chloride and boron trifluoride etherate allowed the obtaining of new reactive oligomers with acetylene groups in the side chain. The possibility of modification of these oligomers in hydrogenation and aminomethylation reactions was demonstrated.
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页码:B272 / B274
页数:3
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