HYDROFORMYLATION OF OLEFINS WITH WATER-SOLUBLE RHODIUM CATALYSTS IN THE PRESENCE OF ALPHA-CYCLODEXTRIN

被引：36
作者：
ANDERSON, JR
CAMPI, EM
JACKSON, WR
机构：
[1] Department of Chemistry, Monash University, Clayton Vic.
来源：
CATALYSIS LETTERS | 1991年 / 9卷 / 1-2期
关键词：
OLEFIN HYDROFORMYLATION; RHODIUM CATALYSIS; WATER SOLUBLE PHOSPHINES; ALPHA-CYCLODEXTRIN;
D O I：
10.1007/BF00769081
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Hydroformylation of hex-1-ene using a water soluble rhodium catalyst HRh(CO)[PPh2(m-C6H4SO3Na)]3 (HRh(CO)(TPPMS)3) (I), gives lower yields when alpha-cyclodextrin is added to the biphasic reaction system implying an interaction between the cyclodextrin and rhodium catalyst.
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页码：55 / 58
页数：4
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