MICROEMULSION POLYMERIZATION OF METHYL-METHACRYLATE WITH THE FUNCTIONAL MONOMER N-METHYLOLACRYLAMIDE

被引：21

作者：

MACIAS, ER ^{[1
]}

RODRIGUEZGUADARRAMA, LA ^{[1
]}

CISNEROS, BA ^{[1
]}

CASTANEDA, A ^{[1
]}

MENDIZABAL, E ^{[1
]}

PUIG, JE ^{[1
]}

机构：

[1] UNIV GUADALAJARA,DEPT INGN QUIM,GUADALAJARA 44430,JALISCO,MEXICO

来源：

COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS | 1995年 / 103卷 / 1-2期

关键词：

METHYL METHACRYLATE; N-METHYLOLACRYLAMIDE; MICROEMULSION POLYMERIZATION;

D O I：

10.1016/0927-7757(95)03209-V

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

In this work, the synthesis of a functional copolymer of methyl methacrylate and N-methylolacrylamide (NMA) in microemulsions prepared with Aerosol OT is reported. The effects of type of initiator and amount of functional monomer on the reaction kinetics were studied. The rate of reaction and final conversion increase as the amount of NMA in the parent microemulsions increases. Copolymer formation was verified by IR spectroscopy and differential scanning calorimetry. IR spectroscopy also demonstrated that the functional monomer was incorporated preferentially at the beginning of the reaction, suggesting that initiation takes place in the aqueous phase.

引用

页码：119 / 126

页数：8

共 28 条

[1] BARTON J, 1987, MAKROMOL CHEM, V188, P693
[2] BRANDRUP J, 1989, POLYM HDB
[3] CANDAU F, 1992, POLYM ORG MEDIA
[4] DELGADOCORDOVA S, THESIS U GUADALAJARA
[5] EDELHAUSER H, 1959, J POLYM SCI POL CHEM, V35, P243
[6] SYNTHESIS AND CHARACTERIZATION OF COPOLYMERS OF STYRENE AND N-METHYLOLACRYLAMIDE
FRIAS, JB
LOPEZ, FJ
ALONSO, N
MENDIZABAL, E
PUIG, JE
[J]. POLYMER BULLETIN, 1993, 31 (03) : 285 - 291
[7] FRIAS JB, 1993, SOC PLAST E, V39, P3460
[8] EFFECT OF SURFACTANTS ON POLYMERIZATION OF ACRYLAMIDE IN AQUEOUS SOLUTIONS
FRIEND, JP
ALEXANDE.AE
[J]. JOURNAL OF POLYMER SCIENCE PART A-1-POLYMER CHEMISTRY, 1968, 6 (7PA1): : 1833 - &
[9] Hidalgo M., 1991, J APPL POLYM SCI APP, V49, P103
[10] KAMOGAWA S, 1958, KOGYO KAGAKU ZASSHI, V61, P1024

← 1 2 3 →