LYCORICIDINE AND PANCRATISTATIN ANALOGS FROM CYCLOPENTADIENE

被引：63

作者：

BANWELL, MG ^{[1
]}

COWDEN, CJ ^{[1
]}

GABLE, RW ^{[1
]}

机构：

[1] AUSTRALIAN NATL UNIV,RES SCH CHEM,CANBERRA,ACT 0200,AUSTRALIA

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1994年 / 24期

关键词：

D O I：

10.1039/p19940003515

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Concise synthetic routes from cyclopentadiene 4 to the lycoricidine and pancratistatin analogues 13. 14 and 17 have been developed.:The key step involved the silver isocyanate promoted ring opening of the gem-dibromocyclopropane 6 to give, after interception of the intermediate isocyanates by added methanol, the carbamates 7 and 8. The X-ray crystal structures of compounds 13 and 16 have been determined.

引用

页码：3515 / 3518

页数：4

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