ANALYSIS OF TRACE OXYGENATED HYDROCARBONS IN THE ENVIRONMENT

被引:15
作者
PIEROTTI, D [1 ]
机构
[1] HARVARD UNIV,DEPT EARTH & PLANETARY SCI,CAMBRIDGE,MA 02138
关键词
analysis; Oxygenated hydrocarbons; sampling;
D O I
10.1007/BF00115780
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
A technique has been developed which can measure low-molecular-weight (C2-C5) oxygenated hydrocarbons down to concentrations of less than 10 parts per trillion (10-12) in the atmosphere. The method uses cryogenic trapping of trace gases from the air, and two-dimensional gas chromatography (2DGC) with flame ionization and photo-ionization detectors to analyze the samples. The method has been used to make extensive measurements in the field, and it is capable of measuring all of the C2-C5 carbonyl compounds in clean tropospheric air. The 2DGC analytical system also makes it possible to prepare accurate, reproducible standards of the low-molecular-weight oxygenated hydrocarbons at trace levels. © 1990 Kluwer Academic Publishers.
引用
收藏
页码:373 / 382
页数:10
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