O2CC6H4C6H4CO2(SnPh3)(2)center dot 4H(2)O AND HO2CC6H4C6H4CO2SnBu2Cl: SYNTHESIS AND INFRARED STUDY

被引:0
|
作者
Mbaye, Abdou [1 ]
Diop, Cheikh Abdoul Khadir [1 ]
Diop, Libasse [1 ]
机构
[1] Univ Cheikh AntaDiop, Fac Sci & Tech, Dept Chim, Lab Chim Minerale & Analyt, Dakar, Senegal
来源
SCIENTIFIC STUDY AND RESEARCH-CHEMISTRY AND CHEMICAL ENGINEERING BIOTECHNOLOGY FOOD INDUSTRY | 2014年 / 15卷 / 04期
关键词
infinite chain; infrared spectroscopy; monochelating ligand; monodentate; octahedral; oligomer; trigonal bipyramidal;
D O I
暂无
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
When the diphenic acid HO2CC6H4C6H4CO2H is allowed to react with SnBu2Cl2 or SnPh3OH, HO2CC6H4C6H4CO2. SnBu2Cl (A) and O2CC6H4C6H4CO2(SnPh3)(2)center dot 4H(2)O(B) were obtained and characterized by infrared spectroscopy. The structures are an infinite chain or an oligomer, the diphenic anion being a monodentate or a monochelating ligand. The environment around the tin centers is trigonal bipyramidal or octahedral.
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页码:357 / 360
页数:4
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